Steuerung der Rotation eines Guanidiniumkations durch Kation‐π‐Wechselwirkungen
Ein Lanthanid‐π‐Container wurde für die Bindung eines Guanidiniumkations in dessen aromatischer Kavität mittels Kation‐π‐Wechselwirkungen verwendet. Röntgenkristallographie und Festkörper‐NMR‐Spektroskopie bei schneller Rotation um den magischen Winkel wurden verwendet, um die zugrundeliegenden Wirt‐Gast‐Interaktionen zu untersuchen.
Hannah Busch +12 more
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Octahedral (DFPD)6CdCl8:10%Sb and tetrahedral (DFPD)2CdCl4·H2O:5%Sb exhibit distinct luminescence dictated by coordination geometry. Solvent‐induced reversible phase transformation enables dynamic switching between yellow and deep‐orange emission. Combined experimental and computational studies elucidate the luminescence mechanisms, and the reversible ...
Zhe Tang +7 more
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Homochiral Cu(I) cyanide complexes based on 2,2’‐bis(diphenylphosphino)‐1,1’‐binaphthyl (BINAP) form melt‐quenched and desolvation‐derived metal–organic glasses that exhibit circularly polarized thermally activated delayed fluorescence (TADF) at room temperature, enabling processable chiroptical materials.
Zeyu Fan +5 more
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Phylogenomic analysis of the collagen-like BclA proteins in <i>Clostridioides difficile</i>. [PDF]
Cid-Rojas F +5 more
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A Clinically Ultrasound Fusion Visual Prediction Model for Childhood Irreducible Small-Bowel Intussusception. [PDF]
Qiang H +5 more
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Hydrogels Incorporating Donor-Acceptor Stenhouse Adducts as a Platform for Photoinduced, On-Off Switchable Release of Small Molecule Cargos. [PDF]
Dell TN +10 more
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D614G reshapes allosteric networks and opening mechanisms of SARS-CoV-2 spikes. [PDF]
Kearns FL +13 more
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Controlling the Guanidinium Cation Rotation by Cation–π Interactions
A lanthanide π‐container has been employed to trap a guanidinium cation inside the aromatic cavity by cation–π interactions. X‐ray crystallography and solid‐state nuclear magnetic resonance (NMR) spectroscopy at fast magic‐angle spinning (MAS) frequencies have been utilized to probe the underlying host–guest interactions.
Hannah Busch +12 more
wiley +1 more source
Label-free fluorescence lifetime imaging for rapid discrimination of high-grade prostate cancer in fresh biopsy cores: a feasibility study. [PDF]
Bec J +7 more
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Porcine influenza mAbs to H3, H5, and H7 hemagglutinins recognize H3 egg adapted site and target the HA stem. [PDF]
Cayol T +15 more
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