Chiroptical studies on brevianamide B : vibrational and electronic circular dichroism confronted [PDF]
, 2015 Chiroptical spectroscopy, such as electronic circular dichroism (ECD) and vibrational circular dichroism (VCD) are highly sensitive techniques to probe molecular conformation, configuration, solvation and aggregation.
Bultinck, Patrick +7 more
core +2 more sources
Structural Revision and Absolute Configuration of Burnettramic Acid A.
Organic Letters, 2019 The recently discovered antibiotic burnettramic acid A (1) and three new congeners, burnettramic acids C-E (2-4), were identified from the co-cultures of two marine Aspergillus strains.
Jiao Li +7 more
semanticscholar +1 more source
Asymmetric microbial reduction of ketones: absolute configuration of trans-4-ethyl-1-(1S-hydroxyethyl)cyclohexanol [PDF]
, 2009 A set of five fungal species, Botrytis cinerea, Trichoderma viride and Eutypa lata, and the endophytic fungi Colletotrichum crassipes and Xylaria sp., was used in screening for microbial biocatalysts to detect monooxygenase and alcohol dehydrogenase ...
Aleu Casatejada, Josefina +4 more
core +2 more sources
Assigning the absolute configuration of single aliphatic molecules by visual inspection
Nature Communications, 2018 Deciphering absolute configuration of a single molecule by direct visual inspection is the next step in compound identification, with far-reaching implications for medicinal chemistry, pharmacology, and natural product synthesis.
D. Ebeling +7 more
semanticscholar +1 more source
The molecular and crystal structure of (+)-mianserin hydrobromide [PDF]
, 1973 X-ray analysis of crystals of (+)-mianserin hydrobromide (1,2,3,4,10,14b-hexahydro-2-methyl-dibenzol[c,f]pyrazino[1,2-a]azepine) has established the stereochemistry and absolute configuration of this compound (S at 14b).\ud \ud The crystals are ...
Feil, D., Ru, C. van
core +3 more sources
Redetermination and absolute configuration of berkeleydione
Acta Crystallographica Section E: Crystallographic Communications, 2015 The crystal structure of the title compound, berkeleydione [systematic name; (5aS,7R,9S,11R,11aS)-methyl 9-hydroxy-1,1,5,7,9,11a-hexamethyl-14-methylidene-3,8,10-trioxo-1,3,4,5a,6,7,8,9,10,11,11a,12-dodecahydro-7,11-methanocycloocta[4,5]cyclohepta[1,2-c ...
Andrea Stierle +2 more
doaj +1 more source
Redetermination and absolute configuration of atalaphylline
Acta Crystallographica Section E, 2010 The title acridone alkaloid [systematic name: 1,3,5-trihydroxy-2,4-bis(3-methylbut-2-enyl)acridin-9(10H)-one], C23H25NO4, has previously been reported as crystallizing in the chiral orthorhombic space group P212121 [Chantrapromma et al. (2010).
Hoong-Kun Fun +2 more
doaj +1 more source
A Hybrid Multi-Distance Phase and Broadband Spatially Resolved Spectrometer and Algorithm for Resolving Absolute Concentrations of Chromophores in the Near-Infrared Light Spectrum [PDF]
, 2010 For resolving absolute concentration of tissue chromophores in the human adult brain with near-infrared spectroscopy it is necessary to calculate the light scattering and absorption, at multiple wavelengths with some depth resolution.
Cooper, CE +5 more
core +1 more source
Redetermination and absolute configuration of 7α-hydroxyroyleanone
Acta Crystallographica Section E, 2010 The title compound [systematic name: 7α,12-dihydroxy-8,12-abietadiene,11,14-dione or (4bS,8aS,10R)-3,10-dihydroxy-2-isopropyl-4b,8,8-trimethyl-1,4,4b,5,6,7,8,8a,9,10-decahydrophenanthrene-1,4-dione], C20H28O4, is an abietane diterpenoid, which ...
Ibrahim Abdul Razak +4 more
doaj +1 more source
Photoelectron Circular Dichroism as a Probe of Chiral Hydrocarbons
Chemistry, 2022 The sensitivity of Photoelectron Circular Dichroism (PECD) in the angular distribution of photoelectrons, a recent chiral technique, to detect chirality in pure hydrocarbons is investigated in a number of benchmark molecules.
Piero Decleva
doaj +1 more source