Aromatic nitrations by mixed acid. Slow liquid-liquid reaction regime [PDF]
Aromatic nitrations by mixed acid have been selected as a specific case of a heterogeneous liquid-liquid reaction. An extensive experimental programme has been followed using adiabatic and heat-flow calorimetry and pilot reactor experiments, supported by
Alos, M.A. +6 more
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An Innovative Project to Strengthen and Improve the Knowledge Acquisition in the Degree in Chemistry Using e-Learning Tools [PDF]
Comunicació presentada a EDULEARN2018, 10th International Conference on Education and New Learning Technologies (July 2-4, 2018, Palma, Mallorca, Spain).The subject "Chemistry II (QU910)" is taught at first academic year (second semester) of the Degree ...
Albiol Chiva, Jaume +10 more
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Polyprotic Acids and Beyond—An Algebraic Approach
For an N-protic acid–base system, the set of nonlinear equations (i.e., mass action and balance laws) provides a simple analytical solution/formula for any integer N ≥ 1.
Harald Kalka
doaj +1 more source
Fluorescence and photostability studies of anthracene-9-carboxylic acid in different media
Electronic absorption and fluorescence spectra of anthracene-9-carboxylic acid (ANCA) were studied in different homogeneous solvents, binary protic/aprotic solvent mixtures and in heterogeneous solutions of the cationic cetyltrimethyl ammonium bromide ...
M. S. A. Abdel-Mottaleb +6 more
doaj +1 more source
Computer-controlled potentiometric acid-base titrations
A system has been developed for computer-controlled potentiometric acid-base titrations consisting of a HP 2114 B computer, a DM 2022 S digital voltmeter and further peripheral devices.
Urs Keller +3 more
doaj +1 more source
We propose herein a theoretical model describing the effect of fatal ethanol poisoning on the equilibria between cell membranes and the surrounding ions.
Aneta D. Petelska +3 more
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Measurement and Modeling of Liquid-Liquid Equilibrium Data of the Ternary system (Water + Butyric Acid + MethylCyclohexanol) at 293.2 K [PDF]
In this research, phase equilibria of the ternary system (water + butyric acid + methylcyclohexanol) was investigated and experimental data of liquid-liquid equilibrium were obtained at 293.2 K and ambient pressure.
Sina Shekarsaraee, Bahareh Bussary
doaj +1 more source
The anodic oxidation of bases in the solvent m-cresol [PDF]
The oxidation of bases in the solvent m-cresol was investigated by polarography, voltammetry at the rotating platinum disc electrode and by chronopotentiometry. It was shown that the m-cresolate ion is the electroactive species in this reaction.
Bos, M., Dahmen, E.A.M.F.
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Fluid phase equilibria of the reacting mixture in the dimethyl carbonate synthesis from supercritical CO2 [PDF]
In order to investigate the dimethyl carbonate synthesis from methanol and supercritical CO2, the thermodynamic behaviour of the reacting mixture, i.e. the quaternary methanol/CO2/DMC/water mixture, has to be known.
Badens, François +3 more
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SN1 Reactions in Supercritical Carbon Dioxide in the Presence of Alcohols: the Role of Preferential Solvation [PDF]
Ethanol (3b) inhibits SN1 reactions of alkyl halides 1 in supercritical carbon dioxide (scCO2) and gives no ethers as products. The unexpected behaviour of alcohols 3 in the reaction of alkyl halides 1 with 1,3-dimethoxybenzene (2) in scCO2 under ...
Bagno +38 more
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