Results 21 to 30 of about 3,274,216 (342)
A quantitative Lewis acidity/basicity scale toward boron‐centered Lewis acids has been developed based on a set of 90 experimental equilibrium constants for the reactions of triarylboranes with various O‐, N‐, S‐, and P‐centered Lewis bases in ...
R. Mayer, N. Hampel, A. Ofial
semanticscholar +1 more source
The pKa values of the 6-[2´-(6´-methyl-benzothiazolylazo)]-1,2-dihydroxy-3,5-benzenedisulfonic acid (Me-BDBD) have been determined at 25 °C, in 0.10 mol L-1 NaCl medium by spectrophotometric method.
Regina Terumi Yamaki +5 more
doaj +1 more source
Determination of the pKa for caffeic acid in mixed solvent using the net analyte signal method and ab initio theory [PDF]
Due to the biological effects of phenolic acid components, polyphenol-rich foods are a significant part of human and animal diets. In this study, the acidity constants of caffeic acid (3,4-dihydroxycinnamic acid) in binary mixtures of ethanol–water were ...
Dadras Abbas +6 more
doaj +1 more source
The ammonolysis of esters in liquid ammonia [PDF]
The rates of ammonolysis of alkyl benzoate and phenylacetate esters in liquid ammonia increase with the acidity of the leaving group alcohol and show relatively large Brønsted βlg values of −1.18 and −1.34, respectively, when plotted against the aqueous ...
Atherton, John +2 more
core +1 more source
Spectrophotometric Determination of Acidity Constants of Thiamine in Water, Water-Triton X-100 Micellar Media Solutions [PDF]
In this work the acidity constants of Thiamine in water and water-Triton X-100 micelle media solutions, at 25 °C, have been determined spectrophotometrically.
Mohammad Goodarzi, Tahmineh Goodarzi
doaj
Acidity of edge surface sites of montmorillonite and kaolinite [PDF]
Peer ...
Cheng, Jun +5 more
core +1 more source
Spectrophotometric Determination of Acidity Constants of Some Anthraquinone Derivatives in Methanol-Water Mixtures [PDF]
A spectrophotometric method is used to determine the acidity constants of some derivatives of 9,10-anthraquinone in binary methanol-water mixtures at 25 °C. There is a linear inverse relationship between pKa of all acids and the mole fraction of methanol
Mohammad Mahdi Khodaei +1 more
doaj
Cholic acid, deoxycholic acid, chenodeoxycholic acid, and ursodeoxycholic acid were purified by a foam fractionation method. Using thermogravimetric analysis, the attached water molecule was found to be completely removed from solids of the latter three ...
Y Moroi, M Kitagawa, H Itoh
doaj +1 more source
pH-Mediated Regulation of Polymer Transport Through SiN Pores [PDF]
We characterize the pH controlled polymer capture and transport thorough silicon nitride (SiN) pores subject to protonation. A charge regulation model able to reproduce the experimental zeta potential of SiN pores is coupled with electrohydrodynamic ...
Ala-Nissila, Tapio, Buyukdagli, Sahin
core +2 more sources
CIT-5: a high-silica zeolite with 14-ring pores [PDF]
The synthesis and structure of a new zeolite, CIT-5 (California Institute of Technology Number Five), is described, which possesses one-dimensional pores comprised of 14 T-atoms (tetrahedrally coordinated silicon or aluminium atoms)
Katsuyuki Tsuji +6 more
core +1 more source

