Results 1 to 10 of about 32,171 (212)

Remote Americium Detection Using an Optical Sensor: A D-Optimal Strategy for Efficient PLS-Based Modeling [PDF]

open access: yesSensors
A fiber-optic visible–near-infrared absorption spectroscopy system in a glove box was demonstrated for remote quantification of Am(III) (0–500 µM) and HNO3 (0.1–9 M) using partial least squares regression (PLSR) models.
Luke R. Sadergaski   +4 more
doaj   +2 more sources

Resonant inelastic X-ray scattering tools to count 5 f electrons of actinides and probe bond covalency [PDF]

open access: yesNature Communications
The actinides possess a complex electronic structure, making their chemical and physical properties among the least understood in the periodic table. Advanced spectroscopic tools, able to obtain deep insights into the electronic structure and binding ...
Bianca Schacherl   +22 more
doaj   +2 more sources

The solubility of oxygen in water and saline solutions

open access: yesFrontiers in Nuclear Engineering, 2023
Oxygen is one of the key reaction partners for many redox reactions also in the context of nuclear waste disposal. Its solubility influences radionuclides’ behavior, corrosion processes and even microbial activity.
F. Bok, H. C. Moog, V. Brendler
doaj   +1 more source

Fuel depletion characteristics of MA transmutation in PWR

open access: yesNuclear Materials and Energy, 2022
The minor actinide transmutation in PWR can change its fuel depletion characteristics distinctly. We simulate PWR reactor fuel depletion characteristics of minor actinide different admitting approaches on burnable poison rods for transmutation ...
Fang Liu   +6 more
doaj   +1 more source

Two Unexpected Temperature-Induced Supermolecular Isomers from Multi-Topic Carboxylic Acid: Hydrogen Bonding Layer or Helix Tube

open access: yesMolecules, 2021
Under ambient conditions or 160 °C, two supramolecular isomers, namely [(H4PTTA)(H2O)2(DMF)] and [(H4PTTA)(H2O)3]··Guest (1-L and 1-H, H4PTTA = N-phenyl-N′-phenyl bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxdiimide tetra-carboxylic acid, Guest = DMF and ...
Chunyang Li   +4 more
doaj   +1 more source

Effective coordination numbers from EXAFS: general approaches for lanthanide and actinide dioxides

open access: yesJournal of Synchrotron Radiation, 2022
Extended X-ray absorption fine structure (EXAFS) is a comprehensive and usable method for characterizing the structures of various materials, including radioactive and nuclear materials. Unceasing discussions about the interpretation of EXAFS results for
Anna Romanchuk   +6 more
doaj   +1 more source

Crystal structures of metallocene complexes with uranium–germanium bonds

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2021
The first structural examples of complexes with uranium–germanium bonds are presented, namely, bis[3,5-bis(trifluoromethyl)phenyl-2κC1](hydrido-2κH)(iodido-1κI)bis[1,1(η5)-pentamethylcyclopentadienyl]germaniumuranium(Ge—U), [GeU(C10H15)2(C8H3F6)2HI], and
Michael L. Tarlton   +2 more
doaj   +1 more source

Computational study on distribution feasibility of radioactive waste transmutation in accelerator driven system [PDF]

open access: yesNuclear Technology and Radiation Protection, 2020
In this paper, the feasibility of high-level radioactive waste transmutation in accelerator driven system sub-critical reactor assembly, has been studied for two zone's model and with three different core configurations.
Al Qaaod Amer A.   +4 more
doaj   +1 more source

Assessment of Various Density Functional Theory Methods for Finding Accurate Structures of Actinide Complexes

open access: yesMolecules, 2022
Density functional theory (DFT) is a widely used computational method for predicting the physical and chemical properties of metals and organometals. As the number of electrons and orbitals in an atom increases, DFT calculations for actinide complexes ...
Youngjin Kwon   +2 more
doaj   +1 more source

SAXS study of the formation and structure of polynuclear thorium(IV) colloids and thorium dioxide nanoparticles

open access: yesJournal of Synchrotron Radiation, 2022
Stable actinide colloids and nanoparticles are of interest because of their potential to affect the transportation of radionuclides in the near-field of a nuclear waste repository.
Baihui Zhai   +4 more
doaj   +1 more source

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