Magnetic ordering and its influence on X‐ray spectroscopies
Major Reference Works, Page 163-168., 2023 International Tables for Crystallography is the definitive resource and reference work for crystallography and structural science.
Each of the eight volumes in the series contains articles and tables of data relevant to crystallographic research and to applications of crystallographic methods in all sciences concerned with the ...
Gerrit van der Laan +3 more
wiley +3 more sources
Valence XPS structure and chemical bond in Cs2UO2Cl4 [PDF]
Nuclear Technology and Radiation Protection, 2016 Quantitative analysis was done of the valence electrons X-ray photoelectron spectra structure in the binding energy (BE) range of 0 eV to ~35 eV for crystalline dicaesium tetrachloro-dioxouranium (VI) (Cs2UO2Cl4).
Teterin Yury A. +7 more
doaj +1 more source
Journal of Synchrotron Radiation, 2022 A spectroelectrochemical setup has been developed to investigate radioactive elements in small volumes (0.7 to 2 ml) under oxidation–reduction (redox) controlled conditions by X-ray absorption spectroscopy (XAS).
Richard Husar +6 more
doaj +1 more source
Actinide inverse trans influence versus cooperative pushing from below and multi-center bonding
Nature Communications, 2023 Actinide-ligand bonds with high multiplicities remain poorly understood. Decades ago, an effect known as 6p pushing from below (PFB) was proposed to enhance actinide covalency. A related effect—also poorly understood—is inverse trans influence (ITI). The
Laura C. Motta, Jochen Autschbach
doaj +1 more source
Carbon-sulfur bond strength in methanesulfinate and benzenesulfinate ligands directs decomposition of Np(v) and Pu(v) coordination complexes. [PDF]
, 2020 Gas-phase coordination complexes of actinyl(v) cations, AnO2+, provide a basis to assess fundamental aspects of actinide chemistry. Electrospray ionization of solutions containing an actinyl cation and sulfonate anion CH3SO2- or C6H5SO2- generated ...
Gibson, John K +4 more
core +3 more sources
Frontiers in Nuclear Engineering, 2023 Controlled-potential in situ thin-layer spectropotentiometry was leveraged to generate visible/near-infrared (VIS/NIR) absorption spectral data sets for the development of chemometric models to quantify Np(III/IV/V/VI) oxidation states in HNO3.
Luke R. Sadergaski +3 more
doaj +1 more source
Chemosensors, 2022 The visible-near infrared (Vis-NIR) electronic absorption spectrum of neptunium(V) (NpO2+) comprises numerous f-f electronic transitions with mostly undocumented temperature dependencies.
Luke R. Sadergaski, Kyle Morgan
doaj +1 more source
Comparison of actinides and fission products recycling scheme with the normal plutonium recycling scheme in fast reactors [PDF]
Nuclear Technology and Radiation Protection, 2013 Multiple recycling of actinides and non-volatile fission products in fast reactors through the dry re-fabrication/reprocessing atomics international reduction oxidation process has been studied as a possible way to reduce the long-term potential ...
Salahuddin Asif, Iqbal Masood
doaj +1 more source
Recovery of actinides from actinide-aluminium alloys by chlorination: Part I [PDF]
, 2011 Pyrochemical processes in molten LiCl–KCl are being developed in ITU for recovery of actinides from spent nuclear fuel. The fuel is anodically dissolved to the molten salt electrolyte and actinides are electrochemically reduced on solid aluminium ...
Cassayre, Laurent +6 more
core +1 more source
Catalytic Organic Transformations Mediated by Actinide Complexes
Inorganics, 2015 This review article presents the development of organoactinides and actinide coordination complexes as catalysts for homogeneous organic transformations.
Isabell S. R. Karmel +2 more
doaj +1 more source