Results 191 to 200 of about 71,864 (273)

Navigating Nitration Chemistry: A Practical Guide to Reagents, Mechanisms, and Selectivity

open access: yesAngewandte Chemie, EarlyView.
This review highlights key contributions of modern nitration chemistry, emphasizing sustainable mechanistic platforms and comparing the performance of both organic and inorganic reagents across aromatic, ipso‐, olefin, alkyne, and heteroatom nitration. It provides the community with a clearer, unified perspective on current advances and facilitates the
Harry Lecomte   +2 more
wiley   +2 more sources

Hydrogen Atom Transfer Induces Photodegradation in Carbonyl‐Based Multi‐Resonance TADF Emitters

open access: yesAngewandte Chemie, EarlyView.
Boosting triplet harvesting in N/C═O MR‐TADF emitters unexpectedly induces rapid photodegradation under oxygen‐free conditions. Spectroscopic studies reveal that triplet excited states trigger hydrogen‐atom transfer from solvent to the carbonyl unit, driven by triplet energetics and hydrogen electrophilicity.
Changfeng Si   +4 more
wiley   +2 more sources

Arytenoid Adduction

open access: yesKoutou (THE LARYNX JAPAN), 2011
T. Sanuki, Y. Toya, E. Yumoto
openaire   +3 more sources

Reliability assessment of markerless technologies in biomechanical motion analysis: a performance comparison. [PDF]

open access: yesFront Sports Act Living
Balci IC   +10 more
europepmc   +1 more source

Iron Catalyzed Aryl–Aryl Kumada Cross‐Coupling: A Mechanistic and Computational Investigation

open access: yesAngewandte Chemie, EarlyView.
Despite intense interest, the mechanism of iron‐catalyzed aryl–aryl cross‐coupling remains poorly understood. Combining Mössbauer spectroscopy, kinetics analysis, and DFT computations these studies reveal a novel Fe(I)/Fe(II)/Fe(III) catalytic for aryl–aryl cross‐coupling mediated by an Fe(II) PCNHCP Pincer complex. These findings close a key knowledge
Jatin Panda   +11 more
wiley   +2 more sources

Bis(silylene)‐Mediated N═N Bond Scission of Diazo Compounds

open access: yesAngewandte Chemie, EarlyView.
The carborane‐based bis(silylene) enables unprecedented N═N bond scission in diazodiarylmethanes. While xanthene‐ and aniline‐based scaffolds promote end‐on addition with partial N═N activation, the carborane‐based variant uniquely achieves complete N═N bond scission of Ar2C═N═N compounds, resulting in isolable disilicon nitride imino species.
Yun Xiong, Shenglai Yao, Matthias Driess
wiley   +2 more sources

Step-down biomechanics in unilateral patellofemoral pain: a cross-sectional study of young females. [PDF]

open access: yesBMC Sports Sci Med Rehabil
Lin X   +7 more
europepmc   +1 more source

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