Results 161 to 170 of about 131,158 (306)

Adsorption Isotherm.

open access: yesThe Journal of the Society of Chemical Industry, Japan, 1925
Toshiro Okuno, Kensuke Saito
openaire   +2 more sources

Decoupling Dynamics and Crosslink Stability in Supramolecular Hydrogels Using Associative Exchange

open access: yesAdvanced Materials, EarlyView.
How does reorganization impact the stability of supramolecular hydrogels? In contrast to dissociative crosslink exchange, implementing associative exchange in macroscale DNA hydrogels enables decoupling of reorganization dynamics from thermal and mechanical stability.
Pierre Le Bourdonnec   +4 more
wiley   +1 more source

Polymorph‐Specific Electronic Transduction in WO3 during Molecular Sensing

open access: yesAdvanced Materials, EarlyView.
Metal‐oxide polymorphs with similar surface chemistry can nevertheless exhibit distinct sensing properties. In γ‐ and ε‐WO3, analyte adsorption appears comparable; yet, only ε‐WO3 induces a pronounced lattice electronic perturbation that accommodates charge in sub‐conduction band minimum states.
Matteo D'Andria   +6 more
wiley   +1 more source

Science‐Towards‐Technology Breakthrough in CO2 Electroreduction: Multiphysics, Multiscale, and Artificial Intelligence Insights

open access: yesAdvanced Materials, EarlyView.
Electrochemical CO2RR is a key technology for converting CO2 into chemicals, but there remains a gap between “laboratory science” and “engineering practice” in current research. This review establishes a multi‐scale research framework, encompassing atomic‐level characterization, microenvironment regulation, external field‐assisted optimization, and AI ...
Ping Hong   +3 more
wiley   +1 more source

Thermodynamics and Kinetics of CO2 Adsorption on Nanoporous Wv1050 Activated Carbon at 20°c and Pressures Up to 35 Bar

open access: yesChemical Engineering Transactions
Thermodynamic and kinetic investigations are essential to understanding the mechanisms involved in adsorbent-adsorbate interaction and evaluating adsorption capacity and time to achieve separation.
Ana L.N. Santos   +6 more
doaj  

High Charge Carrier Mobility in Non‐Conjugated 3D Covalent Organic Frameworks

open access: yesAdvanced Materials, EarlyView.
A non‐conjugated 3D COF constructed via boronate ester linkages from tetraphenylene and pyrene‐based monomers is reported, which exhibits a high charge carrier mobility of 14 ± 1 cm2 V−1 s−1. ABSTRACT π‐Conjugation, π–π stacking, and long‐range order play a central role in determining charge transport efficiency in organic materials.
Joaquín Almarza   +11 more
wiley   +1 more source

A Biochar‐Based Composite Hydrogel Microenvironment for Enhanced Biocatalysis

open access: yesAdvanced Materials, EarlyView.
This work presents the synthesis of a polyacrylamide hydrogel wherein biomass‐derived biochar is co‐encapsulated with the enzyme horseradish peroxidase (HRP). The resulting composite hydrogel possesses balanced electron‐rich and electron‐deficient domains, creating an optimal microenvironment that concentrates both hydrogen peroxide and phenol ...
Shengzhe Wang   +9 more
wiley   +1 more source

Diverse Cation Exchange in Layered Titanate Nanostructures for Tailored Catalysis

open access: yesAdvanced Materials, EarlyView.
H+(H3O+)‐intercalated layered titanate enables stable intercalation of 42 single‐metal and multication combinations. Alkali‐metal intercalation tunes Rh charge density, yielding an efficient propylene hydroformylation catalyst. These results establish a generalizable intercalation platform for rational catalyst design and provide a library supporting ...
Hyoseok Kim   +15 more
wiley   +1 more source

Positively Charged Polymer‐Brush MOFs for Large‐Area, Pressure‐Resistant Gas Separation Membranes

open access: yesAdvanced Materials, EarlyView.
A universal POPA strategy enables positively charged polymer‐brush MOFs with self‐adaptive interfacial interlocking to resist aggregation under fast processing. This design ensures seamless dispersion within large‐area selective layers, achieving 1 m‐wide roll‐to‐roll fabrication of pressure‐resistant MMCMs with tunable CO2 separation performance ...
Yi Yang   +11 more
wiley   +1 more source

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