Results 131 to 140 of about 13,159 (294)

Upcycling Real‐World Post‐Consumer Polyolefins Plastics Into Light Olefins Via Microwave‐Assisted Processing

open access: yesCarbon Energy, EarlyView.
Microwave‐driven Ru@α‐Fe2O3 selectively upgrades real‐world post‐consumer mixed polyolefin waste into light olefins with high gas yields and olefin selectivity at markedly reduced temperatures compared with conventional thermal pyrolysis. Strong tolerance of additives and feed heterogeneity highlights an energy‐efficient and scalable route for circular
Yi Su   +8 more
wiley   +1 more source

Stereoretentive Nucleophilic Aromatic Substitution Accesses Atropisomeric 4‐Amino‐N‐Arylquinolinium Salts

open access: yesChemistry – A European Journal, EarlyView.
Quinolin‐4‐ones were converted to chloroquinolinium salts, allowing formation of axially chiral aminoquinolinium salts via an enantioretentive SNAr reaction with a variety of amine nucleophiles. The salts have a high rotational barrier, with a racemization half‐life of ∼1000s of years.
Darren Holmes   +5 more
wiley   +1 more source

Nitrooxylation in Organic Synthesis: From Classical Nitrate Ester Formation to Modern Catalytic Strategies

open access: yesChemistry – A European Journal, EarlyView.
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley   +1 more source

Going from Pt to PGM‐free Catalysts: Effects of Ink Compositions on PEM Water Electrolysis

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Optimisation of cathode ink formulations regarding the ratio between catalyst, carbon and binder results in a boost in PEM water electrolysis performance. The optimisation can be transferred from pentlandites to platinum and selenide catalysts, wherein the metal chalcogenides show a stronger performance enhancement.
Janna Wierper   +7 more
wiley   +1 more source

Confinement−Adsorption Synergy in Hybrid Carbon‐Coated Separator Enables Stable High‐Rate Quinone Cathode for Magnesium Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A sulfur‐containing heterocyclic quinone cathode for rechargeable magnesium batteries is coupled with a GO/MWCNTs–COOH separator that establishes a confinement–adsorption regulation mechanism, thereby significantly accelerating Mg2+ reaction kinetics and minimizing active‐material loss.
Xiquan Qi   +3 more
wiley   +1 more source

Redistributing Cobalt and Tungsten From WC–Co Soft Scrap Toward Sustainable Cathode and Coating Materials for Lithium‐Ion Batteries

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A sustainable upcycling strategy transforms tungsten carbide–cobalt (WC–Co) soft scrap into high‐performance cathode materials. Recycled Co with trace nickel (Ni) is resynthesized into stabilized LiCoO2 with superior high‐voltage durability, while the recovered tungsten is further utilized as tungsten trioxide to enhance Ni‐rich cathode interfaces ...
Seulgi Kim   +10 more
wiley   +1 more source

Nanofiber PVA‐Based Membranes Incorporating Functionalized Spanish Broom Derivatives for Sustainable Water Purification

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This study investigates Spanish broom (Spartium junceum) as a renewable source for electrospun composite membranes in sustainable water purification. MCC and biochar were functionalized with eco‐friendly precursors and nanomaterials (i.e., HNT, β‐CDs) to develop hybrid PVA nanofiber composites.
Giulia Rando   +7 more
wiley   +1 more source

Ethylene role in adventitious root formation in Arabidopsis thaliana thin cell layers

open access: yes, 2014
Adventitious roots (ARs) are post-embryonic roots arising from non-pericycle tissues in primary root (PR) and various tissues in aerial organs. ARs are essential for successful vegetative propagation.
FALASCA, Giuseppina   +4 more
core  

Interplanar Potential Difference‐Mediated Efficient Charge Separation in SrLi2Ti6O14 Towards Optimized Photocatalytic Hydrogen Evolution

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The periodic quantum well formed by alternative stacking of SrO and LTO layers facilitates efficient photoinduced charge separation and thus significantly improves its photocatalytic hydrogen production performance. SrLi2Ti6O14 porous microspheres (SLTO PMSs) and SrLi2Ti6O14/TiO2 hollow sphere heterojunctions (SLTO/TiO2 HSs) are fabricated via ...
Nan Zhao   +6 more
wiley   +1 more source

Chemically Modular, Nonfluorinated Polymer Adsorbents for Capturing Per‐ and Polyfluoroalkyl Substances (PFAS)

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Nonfluorinated polymer networks for PFAS adsorption are synthesized using active ester click chemistry. Incorporating Lewis base ligands along with hydrophilic and hydrophobic co‐monomers leads to high PFOA binding efficiency. Ligand basicity and pH are found to play an important role in PFOA sorption.
Lakshay K. Dhamania, Joshua D. Moon
wiley   +1 more source

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