Results 141 to 150 of about 13,159 (294)

Redox‐Active Bisphosphines Based on a W(II)‐Propargyl Complex Backbone

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Three bisphosphine ligands based on tungsten(II) propargyl‐type alkyne complexes were synthesized and characterized. The methanolate derivative was used as a metalla‐ligand for the preparation of a binuclear bisphosphine‐κ2‐PdCl2 complex. In both cases, IR spectroelectrochemistry (IR‐SEC) measurements revealed a successive process following oxidation ...
Friederike M. Hamann   +7 more
wiley   +1 more source

One‐Pot Gold(I)‐Catalyzed Rautenstrauch Rearrangement/Nitrosocarbonyl Hetero‐Diels–Alder Reaction Sequence for the Synthesis of α‐Hydroxylated Cyclopentenones

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The regio‐ and stereoselective synthesis of ring‐fused α‐hydroxy‐2‐cyclopentenones is achieved by a one‐pot gold(I)‐catalyzed Rautenstrauch rearrangement/nitrosocarbonyl hetero‐Diels–Alder reaction/ring opening sequence carried out on suitable propargyl esters followed by selective NO bond cleavage.
Dina Scarpi   +3 more
wiley   +1 more source

Facet‐engineered BiSI nanorods for intelligent distinguishing detection of NO2/H2S mixed gas

open access: yesInfoMat, EarlyView.
Mixed toxic gases such as NO2 and H2S can threaten safety in coal mines and industrial settings, but it is still difficult to monitor them accurately with a simple sensor. In this work, we improved a BiSI‐based room‐temperature gas sensor through crystal facet engineering and combined it with machine learning so that one sensor could distinguish mixed ...
Zhenze Zhou   +4 more
wiley   +1 more source

Chemical Kinetics of 2‐, 4‐, and 2,4‐Seleno‐Uracils at Low Temperatures: Tautomerizations and Rotamerizations on Inert Matrices

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT In the interstellar medium, chemical reactions proceed under conditions vastly different to those on Earth; these include extremely low temperatures and densities and take place in the gas phase and on water–ice grains. Understanding the energetics and more importantly the kinetics of such reactions is of relevance to the consequences on how ...
Judith Wurmel, John M. Simmie
wiley   +1 more source

A Field Guide for Soil Erosion Risk Assessment in Olive Orchards Across Mediterranean Conditions for End‐Users and Stakeholders

open access: yesLand Degradation &Development, EarlyView.
ABSTRACT Soil erosion control poses a crucial challenge to the sustainability of Mediterranean olive groves. To facilitate field‐level decision‐making, we have developed a field guide oriented to use in any type of olive orchard across the Mediterranean.
I. Domenech‐Carretero   +4 more
wiley   +1 more source

Adventitious root formation as an adaptive response to environmental stress

open access: yes, 1993
Item does not contain fulltextFirst International Symposium on the Biology of adventitious Root Formation, Dallas, USA. United States Department of Agriculture.
Voesenek, L.A.C.J.   +3 more
core  

Ambient‐Light‐Activated Rewritable Optical Patterning in Transparent Long‐Afterglow Garnet Ceramics

open access: yesLaser &Photonics Reviews, EarlyView.
This work demonstrates sunlight‐activated rewritable optical information storage in transparent long‐afterglow Y3Al2Ga3O12:Ce (YAGG:Ce) garnet ceramics fabricated via solid‐state sintering with tetraethyl orthosilicate (TEOS) as a sintering aid. By integrating ambient‐light operability, reversibility, and high optical clarity in a robust ceramic host ...
Luyang Hua   +11 more
wiley   +1 more source

PcabHLH58/PcabHLH151 regulates adventitious root development and nitrogen uptake in poplar. [PDF]

open access: yesNat Commun
Wei H   +9 more
europepmc   +1 more source

Atmospheric Corrosion Protection of LPBF Manufactured AlSi10Mg by Combining SiOx‐CVD and PDMS Grafting

open access: yesMaterials and Corrosion, EarlyView.
Hybrid SiOₓ‐CVD/PDMS ultrathin films mitigate atmospheric corrosion of additively manufactured AlSi10Mg. Electrochemical analyses show reduced corrosion currents, increased charge‐transfer resistance, and suppressed pitting due to diminished cathodic activity and limited oxygen and ion transport under NaCl exposure.
Tim Prüßner   +3 more
wiley   +1 more source

Physiological and transcriptome analyses for revealing the mechanism of adventitious root formation in Camellia luteoflora. [PDF]

open access: yesBMC Plant Biol
Wu G   +14 more
europepmc   +1 more source

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