Photolytic Hydrophosphination: Insights Into Catalyzed and Uncatalyzed Processes
Chemistry – A European Journal, EarlyView.Catalyst‐free photolytic hydrophosphination is demonstrated for vinyl arenes and activated alkenes in polar protic (alcohol) solvents. These reactions appear to be closed‐shell, affirming that even ambient light can impact a reaction—a potentially broad influence on even mundane reactions.
Emma J. Finfer +2 more
wiley +1 more source
Flipping the Card With Enantiodivergent Organocatalysis
Chemistry – A European Journal, EarlyView.This minireview elaborates on recent organocatalytic strategies for achieving enantiodivergence—the ability to access both product enantiomers using a single chiral catalyst. It highlights how achiral stimuli, such as solvent polarity and chemical additives, along with minimal catalyst modifications, trigger stereochemical inversions in reactions ...
Debora Iapadre +3 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley +1 more source
ECG changes amongst patients with alcohol withdrawal seizures and delirium tremens
Swiss Medical Weekly, 2006 T Ehmann
doaj +1 more source
Stereoselective Synthesis of β‐C‐glycosides From Exoglycals Through Radical C─C Bond Formation
Chemistry – A European Journal, EarlyView.We describe herein a convenient strategy for the preparation of β‐C‐glycosides via the addition of radical species onto exoglycals. This method is efficient, general and achieved in mild conditions starting from xanthates derivatives and using triethylborane as initiator and 4‐tert‐butylcatechol as hydrogen atom source. This hydroalkylation reaction is
Noémie Murard +2 more
wiley +1 more source
Bupropion Toxicity Presenting As Alcohol Withdrawal Syndrome: A Case Report. [PDF]
CureusNguyen D +3 more
europepmc +1 more source
On Metal Carbonyl Compounds in Catalytic Methanol Synthesis: Detection, Consequences, and Removal
Chemie Ingenieur Technik, EarlyView.Deactivation of Cu/ZnO/Al2O3 catalysts by metal carbonyl compounds in the feed gas is a critical problem in catalytic methanol synthesis. We utilize PTR–MS to identify potential chemical sources, detect contamination in an in‐house CO gas line, and validate filter methods for removing these catalyst poisons before synthesis.
Florian Stappert +4 more
wiley +1 more source
Altered voltage-gated calcium channels in rat inferior colliculus neurons contribute to alcohol withdrawal seizures. [PDF]
Eur Neuropsychopharmacol, 2015 N'Gouemo P.
europepmc +1 more source
A novel bubbling fluid bed reactor for the autothermal pyrolysis of waste plastics
The Canadian Journal of Chemical Engineering, EarlyView.Abstract A new pilot‐scale fluidized bed reactor operated under continuous conditions was developed and tested for the thermal pyrolysis of high‐density polyethylene (HDPE). The study focused on assessing the reliability and operability of the system under different operating conditions (400–550°C), while monitoring mass and energy balances, product ...
Khadija Olivia Ogoula Igouwe +4 more
wiley +1 more source
Case Report: Diagnostic challenge between epileptic seizure and tetany in Albright hereditary osteodystrophy. [PDF]
Front RadiolBurns MD +8 more
europepmc +1 more source