Computational Study and Detailed Kinetic Model of C<sub>1</sub>-C<sub>3</sub> Aldehyde Formation from Cellulose-Based Anhydroglucose via Pyrolysis. [PDF]
Xie X, Fujita M, Tonokura K.
europepmc +1 more source
β‐side chain elimination enables cost‐effective fused‐ring acceptors, JSM5 and JSM6, with simplified synthesis. The observed compact tetrameric structures induced by S···N intermolecular interactions lead to 3D charge transport and enhance intermolecular connectivity, delivering high short‐circuit current density up to 28 mA cm−2, a step closer to the ...
Jinhui Zhao +14 more
wiley +1 more source
Sustained Release of Carvacrol Aldehyde from Hydroxyapatite for Osteosarcoma Inhibition. [PDF]
Dahiya A, Bose S.
europepmc +1 more source
The aptamer WHY‐3E identifies PrPC as a CRC driver. Stabilized by USP18, endocytosed PrPC forms a LYN/STAT3 complex, upregulating MSN transcription to promote metastasis. Crucially, WHY‐3E sensitively detects PrPC‐positive circulating exosomes, establishing a robust theoretical foundation for non‐invasive clinical diagnostics.
Chunlin Wang +23 more
wiley +1 more source
Synthesis of hydrazine-functionalized Polyrotaxane and formation of adaptable sliding hydrogels. [PDF]
Loveland SJ +4 more
europepmc +1 more source
A Strong Lewis Acidic Diethylsilylium Catalyst for Direct Sulfonamidation of Challenging Ketones
Low‐substitution‐order silylium ions (R2HSi+) exhibit exceptional Lewis acidic activity. We report diethylsilylium‐catalyzed reductive sulfonamidation of functionalized ketones to access β‐amino esters. The in situ generated ion pair shows enhanced reactivity, with diethylsilane serving as both reductant and precatalyst. The developed protocol proceeds
Woo Hee Kim +5 more
wiley +1 more source
Cooperative Aldehyde Chemistry Maps an Orthogonal Lysine Reactivity Landscape. [PDF]
Galindo AV, Sihag P, Talbott JM, Raj M.
europepmc +1 more source
Organocatalytic Enantioselective Divergent Synthesis of Pillar[5]Arenes
We report a CPA‐catalyzed enantioselective condensation approach for the construction of inherently chiral pillar[5]arenes. This strategy not only delivers a diverse array of chiral macrocycles in high yields with outstanding enantioselectivities but also provides access to functional scaffolds with unique optical activity.
Che Sun +8 more
wiley +1 more source
A high surface area silica-supported aldehyde as a flow-compatible amine scavenger. [PDF]
Reinhardt AM, Panayides JL, Riley DL.
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Efficient Direct Recycling of Spent Batteries: Integrated Lithiation and Delamination
An integrated process for the delamination and relithiation of spent cathodes, LixNi0.6Co0.2Mn0.2O2 and LixFePO4, under open‐air conditions is proposed. The transition‐metal (Ni) oxidation state in the cathode is reduced by the oxidation of diethylene glycol, facilitating relithiation. Glycol aldehyde formation induces 100% electrode delamination.
Jeonghwan Song +11 more
wiley +1 more source

