Results 91 to 100 of about 30,391 (259)

Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis

European Journal of Organic Chemistry, EarlyView.
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley   +1 more source

The Cyano‐Diels–Alder Reaction: From Nitrile Activation to Functional Molecular Architectures

European Journal of Organic Chemistry, EarlyView.
This Concept Article presents the evolution of the cyano‐Diels–Alder reaction from its early examples to its current development as a valuable synthetic tool for the preparation of N‐heterocycles, fused polycycles and functional chromophores, tracing the key breakthroughs that have transformed this underexplored transformation into a relevant platform ...
Giovanni Bottari
wiley   +1 more source

Developmental pathways to autism in tuberous sclerosis complex: Evidence from a longitudinal cohort

Epilepsia, EarlyView.
Abstract The association between autism spectrum disorder (hereafter referred to as autism) and tuberous sclerosis complex (TSC) is well established, yet the developmental pathways linking genetic mutation, cortical pathology, and epilepsy with autism remain unclear. The Tuberous Sclerosis 2000 Study recruited children newly diagnosed with TSC (N = 125)
Fiona S. McEwen, Abigail K. Runicles, Holan Liang, Emma Woodhouse, Lisa Underwood, Elizabeth Shephard, Edward D. Barker, Fintan Sheerin, Juul W. Steenbruggen, Tuberous Sclerosis 2000 Study Group, John R. W. Yates, Charlotte Tye, Patrick F. Bolton   +12 more
wiley   +1 more source

Recent advances in multifunctional soft robots: A materials–structures–systems co‐design perspective for synergistic integration

FlexMat, EarlyView.
Abstract Soft robots, engineered from highly compliant materials, offer superior adaptability and safety in unstructured environments compared to their rigid counterparts. Recent advancements, fueled by bio‐inspiration and material programmability, have led to the rapid co‐evolution of their core modules: actuation, sensing, protection, energy, and ...
Qiulei Liu, Zicao Peng, Chong Sun, Haitao Yang   +3 more
wiley   +1 more source

Endohedral fullerenes as qubits: From synthesis to quantum computing applications

InfoMat, EarlyView.
Endohedral fullerenes emerge as promising platforms for qubits and qudits. This review surveys the primary synthesis routes, from arc‐discharge to high‐yield molecular surgery. It then details spin manipulation and readout in key systems, including metal‐based, cluster, and nitrogen‐containing fullerenes.
Jeong‐Seok Nam, Jiye Han, Jin‐Myung Choi, Franklin H. Cho, Daniel K. Park, Seunghee Park, Yoshifumi Hashikawa, Yasujiro Murata, Eunsang Kwon, Dong‐Hwan Kim, Junki Kim, Il Jeon   +11 more
wiley   +1 more source

Adaptive Immunity in Marsupials

Journal of Experimental Zoology Part A: Ecological and Integrative Physiology, EarlyView.
Comparison of the marsupial and eutherian adaptive immune systems. ABSTRACT Marsupials diverged from eutherian mammals 125–160 million years ago. Although evolutionarily distinct, both groups of mammals can produce complex adaptive immune responses to antigens with several key differences.
Cassandra L. Jol, Hayley J. Stannard, Julie M. Old   +2 more
wiley   +1 more source

The art of avoidance: bedsite use, antipredator strategies, and predation risk in white‐tailed deer fawns

The Journal of Wildlife Management, EarlyView.
Horizontal visibility, rather than concealment cover, drove fawn bedsite use and predation risk. Greater field of view decreased the odds of coyote predation, likely by facilitated by early detection. As fawns transitioned from hiders to followers, they shifted from using dense overstory concealment to more open overstory that favored improved escape ...
Tyler R. Obermoller, Eric S. Michel, Joseph K. Bump   +2 more
wiley   +1 more source

Niche Based or Neutral Processes? Bacterial Community Assembly in Soil Aggregates During Primary and Secondary Succession

Land Degradation &Development, EarlyView.
ABSTRACT Abiotic and biotic filters shape microbial phylogenetic diversity. Here, we evaluated bacterial phylogenetic diversity in micro‐ and macro‐aggregates across primary and secondary soil successions to assess the relative influence of niche‐based and neutral processes.
Lidong Huang, Eduardo Pérez‐Valera, Daquan Sun   +2 more
wiley   +1 more source

Facilitative Effects of <i>Alnus viridis</i> ssp. <i>fruticosa</i> on <i>Betula nana</i> ssp. <i>exilis</i> Growth in Arctic Alaska. [PDF]

Ecol Evol
Drew JW, Bret-Harte MS, Buchwal A, Ruess R.   +3 more
europepmc   +1 more source

Topographic and Climatic Determinants of Soil Organic Carbon Across Landscapes: A Meta‐Analysis

Land Degradation &Development, EarlyView.
ABSTRACT The soil is the greatest natural store of organic carbon, holding between 1500 to 1550 Pg C of organic carbon at the top 100 cm of the soil globally—roughly twice the carbon pool in the atmosphere. The spatial distribution of this stock is controlled by a complex chain of controls: topographic position regulates the hydrological redistribution,
Vishal Sharma, Syed Hujjat ul Baligah, Tajamul Islam Shah, Shahid Shuja Shafai, Owais Bashir, Syed Sheraz Madhi, S. Naresh Kumar, Ayyandar Arunachalam, Shabir Ahmed Bangroo   +8 more
wiley   +1 more source