In this work, we establish a direct correlation between internal compactness and particle architectural stability, identifying it as a key descriptor of cathode structural integrity. Simultaneously, the capacity contribution and compensation mechanism of ARR are resolved, revealing that the extent of irreversible capacity loss is governed by both the ...
Yizhen Huang +24 more
wiley +1 more source
Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation
Unlocking gallyl nucleophiles: Counterion control enables formation of an unsupported gallyl─gold complex. Gold coordination induces a polarity switch at gallium, enabling cooperative activation of NH3 and related N─H/O─H substrates under mild conditions.
Hellen Videa +3 more
wiley +1 more source
Study on the Hydration Kinetics Characteristics of Low-Calcium Cementitious Materials Based on Alkali-Activated CWM. [PDF]
Zhou S, Li G, Wang J, Zhang K, Liu S.
europepmc +1 more source
Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2
By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin +3 more
wiley +1 more source
Alkalinity-Dependent Dual Role of Sodium Sulfate in Alkali-Activated Slag: From Synergistic Activation to Competitive Inhibition. [PDF]
Ding N +5 more
europepmc +1 more source
Therapeutic Efficacy of Rapamycin in an Experimental Mouse Model of Corneal Alkali Burn. [PDF]
Bhujel B, Lee H, Chung HS, Kim JY.
europepmc +1 more source
Comparative Study on the Performance and Hydration Mechanism of Coal Gangue Cementitious Materials with Different Alkali Activators. [PDF]
Geng C +9 more
europepmc +1 more source
Alkali metal cation effects for rapid C-H activation by iron(0) complexes. [PDF]
Hidalgo N +6 more
europepmc +1 more source
Theoretical Investigation on the Mechanism of Ni<sup>0</sup>(enolate)-Ate Complex-Catalyzed C(sp<sup>2</sup>)-F Bond Activation and the Origin of Alkali Metal Cations Modulating Enantioselectivity. [PDF]
You XX, Zhong RL, Su ZM.
europepmc +1 more source
Paste-Level Evaluation of a Hybrid Silicomanganese Slag-Steel Slag-OPC-Activated Binder: Mechanical Performance, Simplified Carbon Footprint and Mn Leaching Reduction. [PDF]
Duan J, Zhang X, Zhao J, Hua S, Li H.
europepmc +1 more source

