Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation
Unlocking gallyl nucleophiles: Counterion control enables formation of an unsupported gallyl─gold complex. Gold coordination induces a polarity switch at gallium, enabling cooperative activation of NH3 and related N─H/O─H substrates under mild conditions.
Hellen Videa +3 more
wiley +1 more source
Batch-fabrication of all-dielectric vapor cells enabling optically addressed Rydberg atom electrometry. [PDF]
Artusio-Glimpse AB +11 more
europepmc +1 more source
Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective
Ionic liquids (ILs) have gained great attention as safe electrolyte components in recent years. This review elucidates the temperature effects on IL‐based electrolytes from molecular configurations, physicochemical properties, and interfacial chemistry, raises the challenges and design strategies operating at low‐ and HT, providing valuable guidance ...
En Xie +11 more
wiley +1 more source
This work focuses on how to improve the selectivity and activity of electrocatalytic CO2 reduction to C3+ products, by the integration of electrocatalyst and electrolyte co‐design. We summarize key C3+ formation mechanisms and provide a comprehensive reaction network through thermodynamic analysis.
Ling Chen, Damien Voiry, Yan Jiao
wiley +1 more source
Study on the Hydration Kinetics Characteristics of Low-Calcium Cementitious Materials Based on Alkali-Activated CWM. [PDF]
Zhou S, Li G, Wang J, Zhang K, Liu S.
europepmc +1 more source
Revisiting Coulombic Efficiency Paradigm: Electrolyte Additive Design for Lithium Metal Batteries
Coulombic efficiency (CE) is a key metric for screening advanced electrolyte formulations for rechargeable batteries. Combined with interphasial characterizations, statistical analyses of CE data uncover the synergistic interaction between fluorinated additives and salt anions, enabling more precise correlations of chemical functionalities with ...
Qixin Wang +16 more
wiley +1 more source
Alkalinity-Dependent Dual Role of Sodium Sulfate in Alkali-Activated Slag: From Synergistic Activation to Competitive Inhibition. [PDF]
Ding N +5 more
europepmc +1 more source
Therapeutic Efficacy of Rapamycin in an Experimental Mouse Model of Corneal Alkali Burn. [PDF]
Bhujel B, Lee H, Chung HS, Kim JY.
europepmc +1 more source
Comparative Study on the Performance and Hydration Mechanism of Coal Gangue Cementitious Materials with Different Alkali Activators. [PDF]
Geng C +9 more
europepmc +1 more source
Alkali metal cation effects for rapid C-H activation by iron(0) complexes. [PDF]
Hidalgo N +6 more
europepmc +1 more source

