Results 221 to 230 of about 126,640 (272)

Biocatalytic Regioselective C‐Formylation of Resorcinol Derivatives

Angewandte Chemie, EarlyView.
An acyltransferase from Chromobacterium sphagni (CsATase) was identified that catalyzes the regioselective formylation of resorcinol substrates. The formylation of substituted resorcinol derivatives yielded mono‐formylated products with up to 99% conversion and up to 74% isolated yield.
Lilla Gal, Suresh Rohan, Anna Żądło‐Dobrowolska, Bianca Hilweg, Judith Müller, Kai Tittmann, Wolfgang Kroutil   +6 more
wiley   +2 more sources

Band‐Edge Engineering of BiFeO3–KTaO3 Solid Solutions toward Efficient Solar Hydrogen Production

Advanced Energy and Sustainability Research, EarlyView.
This study reports BiFeO3–KTaO3 solid solutions as efficient photocathodes for solar hydrogen production. Combining experiments with density functional theory, the authors demonstrate composition‐driven band‐edge tuning, achieving high photocurrent density and hydrogen generation rates.
Yassine Nassereddine, Manal Benyoussef, Bouchra Asbani, Nitul Rajput, Mimoun El Marssi, Mustapha Jouiad   +5 more
wiley   +1 more source

A Mechanochemical Kolbe–Schmitt Reaction: Catechol Carboxylation Provides Building Blocks for Renewable Plasticizers

Angewandte Chemie, EarlyView.
A mechanochemical Kolbe–Schmitt reaction of disodium catecholate enables the synthesis of mono‐ and dicarboxylated catechols at low temperature and CO2 pressure. Directly derivatizing the resulting carboxylic acid and phenolic moieties in the obtained mixture provides plasticizer blends with efficiencies competitive to commercial benchmarks.
Dries De Vos, Victoria S. Pfennig, Arno Goddé, Robby Vroemans, Tobias Krückel, Nicole Marcinkowska, Ettore Bartalucci, Thomas Wiegand, Carsten Bolm, Bert U. W. Maes   +9 more
wiley   +2 more sources

A critical review of porous adsorbents for air separation: From fundamental insights to rational adsorbent design

AIChE Journal, EarlyView.
Abstract Air separation via selective adsorption using porous adsorbents offers energy‐efficient alternatives to cryogenic distillation for producing high‐purity O2 and N2. Adsorbent efficacy depends on balancing selectivity, durability, and performance consistency across varying conditions. This comprehensive review critically discusses the design and
Tianqi Wang, Daisong Chen, Tianyi Zhang, Boyu Zhang, Ruiqiang Wang, Zhengdong Liu, Mei Hong, Youssef Belmabkhout, Qinfen Gu, Jin Shang   +9 more
wiley   +1 more source

(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications

Angewandte Chemie, EarlyView.
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh, Nicole Hanania, Pinaki Nad, Tipu Alam, Tamir Kish, Ahmad Masarwa   +5 more
wiley   +2 more sources

A Crystalline Mono‐Coordinate Indium(I)‐Phosphaalkenyl

Angewandte Chemie, EarlyView.
The redox neutral carbometallation of a phospha‐alkyne using the dimeric indium(I) compound (InTer)2 is reported. This reaction affords a mono‐coordinate indium(I) compound that can reversibly extrude the phospha‐alkyne upon addition of a Lewis acid. Abstract The synthesis of the mono‐coordinate indium(I) compound In[C(Ad)═PTer] (Ad = 1‐adamantyl, Ter =
Álvaro García‐Romero, Maren Pink, Israel Fernández, Jose M. Goicoechea   +3 more
wiley   +2 more sources

Boosting the Nucleophilicity of the Diphenylphosphide Anion with Crown Ether Supported Heavy Alkali Metals to Facilitate Highly Efficient Catalytic Alkene Isomerisation

Angewandte Chemie, EarlyView.
Here, we report a breakthrough study in catalytic alkene isomerisation using crown ether‐supported alkali metal phosphides in which the activity increases sequentially and significantly as Group One is descended with Cs(18‐crown‐6)PPh2 (1Cs) performing best.
Felix Krämer, Thomas M. Horsley Downie, Robert E. Mulvey   +2 more
wiley   +2 more sources

Encapsulated Non‐Exchangeable Na+ Ions Determining the Upper Limit of Al Inclusion in FAU—A Multiscale Simulation

Angewandte Chemie, EarlyView.
DFT computation, AIMD simulations, machine learning, statistical analysis, and experimental characterization reveal that the upper limit of Al inclusion in FAU zeolite synthesized under hydrothermal conditions is determined by the encapsulated non‐exchangeable Na+ ions.
Qi Dong, Tao Zhang, Chuanhao Zhang, Tong Zhang, Yanze Du, Jinghong Ma, Ruifeng Li, Bo Qin, Haijun Jiao   +8 more
wiley   +2 more sources

A Metallosupramolecular Receptor for Squaraine Dyes Enabling Ultrafast Dark Resonance Energy Transfer

Angewandte Chemie, EarlyView.
A metallosupramolecular receptor binds squaraine dyes with high affinity and enables efficient dark resonance energy transfer (DRET) that generates bright near‐infrared emission with large pseudo‐Stokes shifts. ABSTRACT A metal‐organic cage was obtained by combining acridone‐based dipyridyl ligands with Pd2+ ions. The cage acts as a potent receptor for
Damien W. Chen, Tejas Deshpande, Sybille Collignon, Farzaneh Fadaei‐Tirani, Sascha Feldmann, Kay Severin   +5 more
wiley   +1 more source

Influence of Alkaline Electrolyzed Water on the Strength, Shrinkage Behavior, and Microstructure of Alkali-Activated Fly Ash/Slag Composites. [PDF]

Materials (Basel)
Li L, Wu Y, Wang H, Zhu Z, Wu D, Wang L, Wang N.   +6 more
europepmc   +1 more source