Results 151 to 160 of about 110,454 (254)

1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene

Angewandte Chemie, EarlyView.
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic, Tobias Heitkemper, Niklas Mehner, Maximilian Kubis, Christian P. Sindlinger   +4 more
wiley   +2 more sources

Identification of Potential Roles of Cathepsin B-like in the Response to Alkali Treatment in <i>Macrobrachium nipponense</i>. [PDF]

Int J Mol Sci
Xu M, Zhang W, Xiong Y, Fu H, Qiao H, Jiang S, Jin S.   +6 more
europepmc   +1 more source

Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation

Angewandte Chemie, EarlyView.
Unlocking gallyl nucleophiles: Counterion control enables formation of an unsupported gallyl─gold complex. Gold coordination induces a polarity switch at gallium, enabling cooperative activation of NH3 and related N─H/O─H substrates under mild conditions.
Hellen Videa, Keelan M. Byrne, Tobias Krämer, Antonio J. Martínez‐Martínez   +3 more
wiley   +2 more sources

Okara protein extracted by alternating ultrasonic/alkali treatment and its improved physicochemical and functional properties. [PDF]

Ultrason Sonochem
Tang L, Liu X, Bai S, Zhao D, Guo X, Zhu D, Su G, Fan B, Wang B, Zhang L, Wang F.   +10 more
europepmc   +1 more source

Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation

Angewandte Chemie, EarlyView.
A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang, Irena Efremenko, Thiyagarajan Subramanian, Amit Kumar, Liat Avram, Yael Diskin‐Posner, David Milstein   +6 more
wiley   +2 more sources

Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2

Angewandte Chemie, EarlyView.
By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin, Manting Mu, Max García‐Melchor, Eva Hevia   +3 more
wiley   +2 more sources

Pectic polysaccharides from Tartary buckwheat sprouts: Effects of ultrasound-assisted Fenton treatment and mild alkali treatment on their physicochemical characteristics and biological functions. [PDF]

Ultrason Sonochem
Li WB, Wang J, Qu Mo MM, Li J, Li M, Liu Y, Wang S, Hu YC, Zou L, Wu DT.   +9 more
europepmc   +1 more source

An Enantioselective Alkene Aminoarylation to Form Chiral Indolines via Electrostatically‐Directed Palladium Catalysis

Angewandte Chemie, EarlyView.
Enantioselective aminoarylation of ortho‐allyl anilines is achieved under mild conditions. Key to success is the electrostatically‐directed nature of the key aminopalladation step, achieved by using the sulfonated chiral ligand sSPhos on palladium. A detailed study of electronic trends allows tuning of the sulfonamide protecting group to enable good ...
Max Kadarauch, Paul T. Jirsch, H. Erik Diepers, Hamzah Sharif, Robert J. Phipps   +4 more
wiley   +2 more sources

N-glycoproteomic profiling reveals structural and functional alterations in yellow primary preserved egg white under saline-alkali treatment. [PDF]

Food Chem X
Qi Q, Shi D, Su W, Mu Y.
europepmc   +1 more source

The Formation of Lysinoalanine during the Treatment of Wool with Alkali [PDF]

Biochemical Journal, 1967
M C, Corfield, C, Wood, A, Robson, M J, Williams, J M, Woodhouse   +4 more
openaire   +2 more sources