Results 131 to 140 of about 121,575 (333)

Visible light-mediated gold-catalysed carbon(sp2)-carbon(sp) cross-coupling. [PDF]

, 2016
A dual photoredox and gold-catalysed cross-coupling reaction of alkynyltrimethylsilanes and aryldiazonium tetrafluoroborates is described. The reaction proceeds through visible-light mediated oxidative addition of aryldiazoniums, transmetalation of ...
Kim, Suhong, Rojas-Martin, Jaime, Toste, F Dean   +2 more
core   +1 more source

Improving Ionic Conformality Across Polymer Electrolyte|Electrode Interfaces

Advanced Materials, EarlyView.
Polymer electrolytes typically form physically intimate electrode interfaces but often fail to maintain continuous ionic pathways, critically limiting battery performance. Through strategic compositional design, this study introduces a molecular ionic composite electrolyte that effectively reduces interfacial ionic depletion, ensuring consistent ion ...
Jungki Min, Nicholas F. Pietra, Callum Connor, Zhaohui Liang, Erin C. Jackson, Lei Tao, Dawei Xia, Xu Feng, Dominik Wierzbicki, Seong‐Min Bak, Robert B. Moore, Louis A. Madsen, Feng Lin   +12 more
wiley   +1 more source

Multi-redox indenofluorene chromophores incorporating dithiafulvene donor and ene/enediyne acceptor units

Beilstein Journal of Organic Chemistry
Large donor–acceptor scaffolds derived from polycyclic aromatic hydrocarbons (PAHs) with tunable HOMO and LUMO energies are important for several applications, such as organic photovoltaics.
Christina Schøttler, Kasper Lund-Rasmussen, Line Broløs, Philip Vinterberg, Ema Bazikova, Viktor B. R. Pedersen, Mogens Brøndsted Nielsen   +6 more
doaj   +1 more source

Operando X‐ray Spectroscopy Study of Pd and Pd–Au Laterally Condensed Catalysts during Selective Acetylene Hydrogenation: The Role of Carbon

Advanced Materials, EarlyView.
The selective hydrogenation of acetylene over laterally condensed Pd and Pd–Au catalysts (LCCs) was investigated using operando X‐ray absorption and photoelectron spectroscopy in combination with density functional theory. Pd‐LCCs were found to incorporate significantly more carbon into the metal lattice than Pd–Au LCCs, where the carbon uptake governs
Eylül Öztuna, Thomas Götsch, Daniel Cruz, Patrick Zeller, Olga V. Vinogradova, Zehua Li, Christian Rohner, Franz‐Philipp Schmidt, Zahra Gheisari, Alexander Steigert, Martin Muske, Michael Hävecker, Eugen Stotz, Iryna Antonyshyn, Frank Girgsdies, Olaf Timpe, Thomas Lunkenbein, Vanessa J. Bukas, Karsten Reuter, Robert Schlögl, Katarzyna Skorupska, Axel Knop‐Gericke, Beatriz Roldán Cuenya   +22 more
wiley   +1 more source

Engineering Bilayer Tandem Catalysts on Si‐Based Photocathodes for High‐performance CO2 Reduction to Produce Methane

Advanced Materials, EarlyView.
A Cu/Ag‐Cu bilayer tandem catalyst is designed for a pyramid‐structured p‐Si photocathode, creating multiple and functionally distinct interfaces tailored to specific reaction steps and intermediate stabilization. This Cu/Ag‐Cu‐decorated p‐Si photocathode exhibits both high photocurrent and good selectivity for photoelectrochemical CO2 reduction to CH4.
Hao Wu, Shenghe Si, Haitao Wang, Changlai Wang, Rongchi Dai, Jianuo Li, Shohei Fukaya, Zhenhua Pan, Yujie Xiong, Noritaka Usami, Koyo Norinaga, Yasuyoshi Kurokawa, Suchada Sirisomboonchai, Dong Liu, Qian Wang   +14 more
wiley   +1 more source

Directed Functionalization of Recombinant Spider Silk Nonwoven Membranes with Antibodies Using Non‐Canonical Amino Acids

Advanced Materials, EarlyView.
A recombinant spider silk protein was functionalized by incorporating genetically encoded bio‐orthogonal reactive azido‐groups. The azido‐functionalized proteins were produced in a scalable biotechnological process, and particles, films, as well as nanofibers were established as anchorage for fully functional antibodies via site‐specific bio‐orthogonal
Claudia Lacombe, Charlotte Leonhardt, Martin Humenik, Birgit Wiltschi, Thomas Scheibel   +4 more
wiley   +1 more source

Polarize the Solvent to Regulate the Intermediate Phase and Dynamic Crystallization of Perovskite Films

Advanced Materials, EarlyView.
A solvent engineering strategy using polar polymers is introduced to regulate perovskite crystallization dynamics in solar cells. Strongly polarized fluorinated groups stabilize the intermediate phase and control solvent exfoliation, leading to high‐quality films with suppressed defects.
Zhuoqiong Zhang, Yunfan Wang, Weizhen Wang, Yulan Huang, Shanchao Ouyang, Yonggui Sun, Fei Wang, Xianfang Zhou, Guichuan Xing, Shu Kong So, Guozhong Xing, Hanlin Hu, Songhua Cai, Sai‐Wing Tsang, Tom Wu   +14 more
wiley   +1 more source

Nonmethane hydrocarbon measurements in the North Atlantic Flight Corridor during the Subsonic Assessment Ozone and Nitrogen Oxide Experiment [PDF]

, 2000
Mixing ratios of nonmethane hydrocarbons (NMHCs) were not enhanced in whole air samples collected within the North Atlantic Flight Corridor (NAFC) during the fall of 1997.
Anderson, BE, Blake, DR, Blake, NJ, Chen, TY, Fuelberg, HE, Kondo, Y, Lopez, JP, Rowland, FS, Sachse, GW, Simpson, IJ, Sive, BC, Thompson, AM, Vay, SA   +12 more
core  

Design of High‐Energy Anode for All‐Solid‐State Lithium Batteries–A Model with Borohydride‐Based Electrolytes

Advanced Materials Interfaces, EarlyView.
This study proposes a function‐sharing anode design to enable nonmetallic lithium insertion while maintaining intimate interfacial contact with the solid‐state electrolyte. A combination of lithium‐compatible and conformable borohydrides, highly conformable indium metal, less‐graphitized acetylene black, and a layer of highly graphitized massive ...
Keita Kurigami, Akihiro Ishii, Itaru Oikawa, Hitoshi Takamura   +3 more
wiley   +1 more source

Radical reactions of xanthates: annulation of the cyclopentene ring [PDF]

Journal of the Serbian Chemical Society, 2007
Homoallylic radicals, generated from the corresponding xanthates, react with terminal alkynes to give cyclopentene derivatives in moderate yields.
AHMED MOHAMED ELHESHI, VESELIN MASLAK, RADOMIR N. SAICIC   +2 more
doaj