Results 201 to 210 of about 71,058 (285)

Pyridinium-Fused 1,3-Selenazoles via Cyclizations of 2-Pyridylselenyl Chloride with Alkynes: Synthesis, Structures, and Antifungal Properties. [PDF]

open access: yesInt J Mol Sci
Dukhnovsky EA   +9 more
europepmc   +1 more source

Forcing the Side‐on π‐Coordination of a C≡C Triple Bond to Technetium Using the As,CC,As Alkyne Pincer Ligand 1,2‐Bis(2‐(diisopropylarsaneyl)‐4‐(trifluoromethyl)phenyl)Ethyne

open access: yesAngewandte Chemie International Edition, EarlyView.
Technetium alkyne complexes have eluded isolation for decades with the only indicators for their existence being the isolation of vinylidene carbenes or their follow‐up reaction products despite plentiful of reports for neighboring elements. Stable, crystalline Tc(III) and Tc(V) alkyne complexes (and their Re analogs) have now been prepared and fully ...
Maximilian Roca Jungfer   +5 more
wiley   +1 more source

Oxidative rearrangement of alkynes to chiral α-arylalkanoic esters. [PDF]

open access: yesChem Sci
Alkahtani R   +10 more
europepmc   +1 more source

The H-Pd···N-H metal-ligand dual-atom sites synergistically catalyzed alkyne semi-hydrogenation with complete Z-selectivity. [PDF]

open access: yesNat Commun
Ma H   +16 more
europepmc   +1 more source

Photoinduced polarity-mismatched transformations of isoquinolines into naphthalenes. [PDF]

open access: yesNat Commun
Zhang C   +6 more
europepmc   +1 more source

Aziridination of a Single Carbon Atom in Alkenes via Energy Transfer Catalysis

open access: yesAngewandte Chemie International Edition, EarlyView.
Contrary to traditional alkene aziridination via (formal) nitrene transfer, we herein report a strategy that achieves intermolecular aziridination of a single alkene carbon atom and installs an additional group at the other. Enabled by metal‐free energy transfer (EnT) catalysis, alkenyl boronates and silanes are transformed into reactive intermediates ...
Fritz Paulus   +7 more
wiley   +1 more source

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