Results 161 to 170 of about 35,378 (308)

N‐Doping Activated Presodiation Enhances Sodium‐Ion Provision in Hard Carbon Anodes

open access: yesAdvanced Science, EarlyView.
Introducing pyrrolic‐N sites enables efficient presodiation and stronger PF6− capture, thus pre ‐ forming a robust inorganic‐rich SEI layer in hard carbon anodes. ABSTRACT Hard carbon (HC) is considered the most promising anode material for commercial sodium‐ion batteries (SIBs), yet it still faces critical challenges such as low initial Coulombic ...
Hua Lin   +8 more
wiley   +1 more source

Carboxyphenolate Coordination Frameworks for High‐Voltage Calcium Storage

open access: yesAdvanced Science, EarlyView.
A hexaanionic carboxyphenolate coordination framework, Ca2‐M‐THBPD (M = Mg, Ca, Ba), exhibits ligand‐centered enolate‐quinonoid redox activity enabling tunable, high‐voltage Ca2+ storage (3.5 V vs Ca2+/Ca) modulated by spectator cations. The amorphous structure accommodates reversible divalent‐ion insertion, contributing to enhanced cycling stability ...
Vasudeva Rao Bakuru   +12 more
wiley   +1 more source

In Situ Hybrid Solid-State Electrolytes for Lithium Battery Applications

open access: yes
International audienceThe translation of inorganic–polymer hybrid battery materials from laboratory-scale to industry-relevant battery manufacturing processes is difficult due to their complexity, scalability, and cost and the limited fundamental ...
Villaluenga, Irune   +9 more
core   +1 more source

Electrochemically Induced Interphase by Complex Hydride Anions in Argyrodite Solid Electrolytes for Stable Lithium Metal All‐Solid‐State Batteries

open access: yesAdvanced Science, EarlyView.
Complex hydride anion substitution in argyrodite electrolytes has attracted attention for improving interfacial stability, yet the influence of these anions at Li metal interfaces remains unclear. This work shows that electrochemically formed BH4−‐derived interphases enable stable high‐current full‐cell cycling.
Sangho Lee   +13 more
wiley   +1 more source

Fluoroacetonitrile‑Based Gel Polymer Electrolytes for Fast‑Charging Lithium Metal Batteries

open access: yesAdvanced Science, EarlyView.
A gel polymer electrolyte using fluoroacetonitrile (FAN) as the solvent and fluoroethylene carbonate (FEC) and LiNO3 as additives is proposed for fast‐charging lithium metal batteries. These additives are preferentially reduced on the lithium metal anode surface to form a stable SEI layer, effectively suppressing the reductive decomposition of FAN.
Zuoxin Yang   +5 more
wiley   +1 more source

Rational Design of Weakly‐Solvating Molecules for Salt‐In‐Pre‐Ionic‐Liquid Electrolytes for Li Metal Batteries

open access: yesAdvanced Science, EarlyView.
The weakly‐solvating TFMSPyr electrolyte tailors the Li+ solvation structure by suppressing solvent coordination and promoting anion‐dominated solvation. This unique solvation environment induces preferential anion decomposition at electrode interfaces, forming robust inorganic rich S/CEI.
Bishnu P. Thapaliya   +11 more
wiley   +1 more source

Sintered Cathodes for All-Solid-State Structural Lithium-Ion Batteries

open access: yes, 2017
All-solid-state structural lithium ion batteries serve as both structural load-bearing components and as electrical energy storage devices to achieve system level weight savings in aerospace and other transportation applications.
Huddleston, William   +2 more
core   +1 more source

Solid-state battery test cell for multi-technique operando monitoring of lithium/polymer electrolyte interphase

open access: yes
International audienceMonitoring and understanding the complex interactions taking place at the numerous interphases between different components and materials in solid-state batteries is key to improve both their performance and lifetime.
Genies, Sylvie   +6 more
core   +1 more source

Mechanically Adaptive Polyimide Interfaces for Stable High‐Voltage NCM–Sulfide All‐Solid‐State Batteries

open access: yesAdvanced Science, EarlyView.
A mechanically adaptive polyimide interface dynamically stabilizes single‐crystal cathodes in sulfide all‐solid‐state batteries. By integrating robust chemical coordination with viscoelastic compliance, this smart coating suppresses parasitic reactions and accommodates cyclic volume expansion.
Jiatao Wu   +8 more
wiley   +1 more source

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