Results 1 to 10 of about 62,031 (280)

Efficient allylation of carbonyl compounds with allyl chlorides in water [PDF]

open access: yesARKIVOC, 2004
A novel mediation system, Zn-InCl3 (cat.)/NH4Cl was employed in the Barbier–type allylation. As a result, the allylation with allyl chloride in water took place smoothly under mild conditions. Various aldehydes and even ketones could be employed to afford the corresponding alcohols in high yields.
Ailing Hui   +4 more
doaj   +2 more sources

Design, synthesis, and SAR study of isopropoxy allylbenzene derivatives as 15-lipoxygenase inhibitors [PDF]

open access: yesIranian Journal of Basic Medical Sciences, 2020
Objective(s): Allylbenzenes have been recently developed as inhibitors of lipoxygenases. They decrease peroxidation activity via mimicking 1,4-unsaturated bonds of fatty acids by their allyl portion.
Mina Mousavian   +5 more
doaj   +1 more source

An infrared investigation of the catalyst formation in the system Ni(acac)2, C3H4, (iBu)3AL for propadiene polymerization [PDF]

open access: yes, 1977
The catalyst formation in the system Ni(acac)2, C3H4, (iBu)3Al was investigated by means of infrared spectroscopy. It was found that the Al(acac)3 and (iBu)2Al(acac) formed are both by-products of catalyst formation without a catalytic activity.
Berkel, P.C.J.M. van   +3 more
core   +10 more sources

Comparative Analysis of Volatile Flavor Compounds in Seven Mustard Pastes via HS-SPME–GC–MS

open access: yesMolecules, 2023
To identify the volatile flavor components in mustard paste (MP), the volatile compounds in seven MPs available on the market were isolated and analyzed by headspace solid-phase microextraction combined with gas chromatography–mass spectrometry.
Miao Liang   +5 more
doaj   +1 more source

Chemical Constituents, In Vitro Antioxidant Activity and In Silico Study on NADPH Oxidase of Allium sativum L. (Garlic) Essential Oil

open access: yesAntioxidants, 2021
Allium sativum L., also known as garlic, is a perennial plant widely used as a spice and also considered a medicinal herb since antiquity. The aim of this study was to determine by gas chromatography–mass spectrometry (GC–MS) the chemical profile ...
Oscar Herrera-Calderon   +5 more
doaj   +1 more source

Nitrile Oxide, Alkenes, Dipolar Cycloaddition, Isomerization and Metathesis Involved in the Syntheses of 2-Isoxazolines

open access: yesMolecules, 2023
The involvement of 1,3-dipolar cycloaddition (1,3-DP), double bond migration, metathesis, and nitrile oxide (including in situ-generated nitrile oxide) as dipoles, together with the C=C bond containing dipolarophiles, in the syntheses of 2-isoxazolines ...
Stanisław Krompiec   +7 more
doaj   +1 more source

A Novel Family of [1,4]Thiazino[2,3,4-ij]quinolin-4-ium Derivatives: Regioselective Synthesis Based on Unsaturated Heteroatom and Heterocyclic Compounds and Antibacterial Activity

open access: yesMolecules, 2021
A novel family of [1,4]thiazino[2,3,4-ij]quinolin-4-ium derivatives was synthesized by annulation reactions of 8-quinolinesulfenyl chloride with unsaturated heteroatom and heterocyclic compounds.
Vladimir A. Potapov   +3 more
doaj   +1 more source

Bioactive Compounds in Dietary Spices and Medicinal Plants [PDF]

open access: yesJournal of Agronomy, Technology and Engineering Management, 2022
Aim of this review is to show the most important bioactive compounds in hot spices such as black pepper (Piper nigrum L.), chilli pepper (Capsicum annuum L.) and medicinal plant such AS garlic (Allium sativum L.), and its modes of action ...
Nikola Puvača
doaj   +1 more source

The ethnobotanical, bioactive compounds, pharmacological activities and toxicological evaluation of garlic (Allium sativum): A review

open access: yesPharmacological Research - Modern Chinese Medicine, 2023
Background: Garlic (Allium sativum) is a medicinal plant exploited for its diverse pharmacological benefits and used as a cooking spice globally. In traditional Chinese medicine, garlic is prepared and served in different forms such as syrup, extract ...
Benedict Chukwuebuka Okoro   +9 more
doaj   +1 more source

Nickel(0)-catalyzed divergent reactions of silacyclobutanes with internal alkynes

open access: yesNature Communications, 2022
Transition metal-catalyzed reactions of silacyclobutanes to access structurally diverse organosilicon compounds have attracted attention in recent years.
Xi-Chao Wang   +3 more
doaj   +1 more source

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