Results 21 to 30 of about 62,031 (280)

ANTIOXIDANT AND TOXICITY ACTIVITY IN VITRO OF TWELVE SAFROLE DERIVATIVES [PDF]

, 2014
Indexación: Web of Science; Scielo.The aim of this study was to determine the influence of substituents in aromatic ring and the side chain of safrole on the antioxidant capacity and toxicity of twelve synthetic derivatives of safrole (S1-S12).
CARRASCO, HÉCTOR, ESPINOZA, LUIS, HIDALGO, MARÍA ELIANA, MADRID, ALEJANDRO, PAVÉZ, CATALINA   +4 more
core   +1 more source

Deodorant Activity of Black Cumin Seed Essential Oil against Garlic Organosulfur Compound

Biomolecules, 2021
The deodorant activity of black cumin (Nigella sativa L.) seed, a spice used to flavor curry and vegetable foods in Southwest Asia, against garlic (Allium sativum L.) organosulfur compounds related to human malodor was evaluated.
Yuri Yoshioka, Shinichi Matsumura, Masanori Morimoto   +2 more
doaj   +1 more source

Stereodivergent Synthesis of Three Contiguous Stereogenic Centers by Cu/Ir-Catalyzed Borylallylation. [PDF]

Angew Chem Int Ed Engl
An alkene borylallylation strategy enabled by cooperative Cu/Ir‐catalysis has been uncovered for accessing three contiguous stereogenic centres. This strategy is notable given the inherent challenges of constructing molecules with multiple stereocenters while maintaining high selectivity bearing diverse functional groups.
Das S, Dorn SK, Brown MK.
europepmc   +3 more sources

Highly Diastereo- and Enantioselective Allylboration of Aldehydes using alpha-Substituted Allyl/Crotyl Pinacol Boronic Esters via in Situ Generated Borinic Esters [PDF]

, 2013
Readily available, alpha-substituted allyl/crotyl pinacol boronic esters often give low E/Z selectivity (with Z favored) in reactions with aldehydes. We found that addition of nBuLi to the pinacol boronic ester followed by trapping of the alkoxide with ...
Althaus M., Andersen M. W., Batey R. A., Batey R. A., Beckmann E., Blais J., Brown H. C., Brown H. C., Brown H. C., Brown H. C., Bubnov Y. N., Carosi L., Carosi L., Chemler S. R., Chen M., Chen M., Christine L. Willis, Cmrecki V., Cole T. E., Denmark S. E., Fang G. Y., Flamme E. M., Gonzalez A. Z., Guzman-Martinez A., Hancock K. G., Helen K. Scott, Hesse M. J., Hoffmann R. W., Hoffmann R. W., Hoffmann R. W., Hoffmann R. W., Hoffmann R. W., Hoffmann R. W., Ito H., Jack L.-Y. Chen, Kennedy J. W. J., Kister J., Kliman L. T., Kramer G. W., Lachance H., Larouche-Gauthier R., Matteson D. S., Matthew J. Hesse, Midland M. M., Park J. K., Pelz N. F., Peng F., Peng F., Pietruszka J., Pietruszka J., Posseme F., Pulis A., Ramachandran P. V., Shiner C. S., Sonawane R. P., Stymiest J. L., Varinder K. Aggarwal, Webster M. P., Woodward A. R., Yamamoto Y., Zschage O.   +60 more
core   +2 more sources

Carbocationic cyclisations and rearrangements in the damascone series [PDF]

, 1988
A regio- and stereoselective synthesis of the tertiary chloride 7 is described, involving the Lewis acid catalysed addition of the allyl chloride 6 to isobutene as a key step.
Bäuml, Englbert, Heilmann, Werner, Mayr, Herbert, Rahman, Azizur   +3 more
core   +1 more source

Lead-Promoted Allylation of Carbonyl Compounds with Allyl Bromide [PDF]

Chemistry Letters, 1986
Abstract A lead-promoted allylation of carbonyl compounds with allyl bromide in a Pb/Bu4NBr/Me3SiCl/DMF system has been performed in good yields with high chemoselectivities: RCHO > R1R2CO > R1CH(OH)CO2R2>> R1CO2R2, lactone, (RCO)2O, and RCOCl.
Hideo Tanaka, Shiro Yamashita, Takeshi Hamatani, Youichi Ikemoto, Sigeru Torii   +4 more
openaire   +1 more source

Alkenylation and Allylation of Aldehydes by Using an Ni/Cr/TDAE Redox System [PDF]

, 2001
In 360 females, Bone mineral density (BMD) in lumbar vertebrae (L2-L4) was assessed by quantitative computed tomography (QCT), and the values obtained were compared with the frequency of vertebral transformation or fracture as assessed by lateral scan ...
Goto, Kentaro, Kishimoto, Suguru, Kuroboshi, Manabu, Tanaka, Hideo, Tanaka, Muneaki   +4 more
core   +1 more source

Synthesis of nine safrole derivatives and their antiproliferative activity towards human cancer cells [PDF]

, 2010
Indexación: ScieloSafrole from sassafras oil (Ocoteapretiosa Mez., Lauraceae), is an abundant natural product showing interesting functionality and chemical structure.
Carrasco Altamirano, Héctor, Cuellar Fritis, Mauricio, Espinoza Catalán, Luis, Madrid Villegas, Alejandro, Taborga Liber, Lautaro, Villena García, Joan   +5 more
core   +2 more sources

Synthesis, DFT Study and Antibacterial Activity of some Isoxazoline Derivatives Containing 1,4-benzothiazin-3-one Nucleus Obtained Using 1,3-dipolar Cycloaddition Reaction [PDF]

Iranian Journal of Chemistry & Chemical Engineering, 2020
Novel series of isoxazoline derivatives containing 1,4-benzothiazin-3-one ring (6a-h) were synthesized via 1,3-dipolar cycloaddition reactions of arylnitrile oxides 5a-d on 4-allyl-2-(substituted)-1,4-benzothiazin-3-ones 3 and 4 led to polyheterocyclic ...
Sebbar Nada Kheira, Taha Mohamed Labd, Ellouz Mohamed, Essassi El Mokhtar, Zerzouf Abdelfettah, Karrouchi Khalid, Ouzidan Younes, Mennane Zakaria, T. Mague Joel   +8 more
doaj   +1 more source

Catalytic Enantioselective Synthesis of N-C Axially Chiral N-(2,6-Disubstituted-phenyl)sulfonamides through Chiral Pd-Catalyzed N-Allylation

Molecules, 2022
Recently, catalytic enantioselective syntheses of N-C axially chiral compounds have been reported by many groups. Most N-C axially chiral compounds prepared through a catalytic asymmetric reaction possess carboxamide or nitrogen-containing aromatic ...
Sota Fukasawa, Tatsuya Toyoda, Ryohei Kasahara, Chisato Nakamura, Yuuki Kikuchi, Akiko Hori, Gary J. Richards, Osamu Kitagawa   +7 more
doaj   +1 more source