Copper-catalyzed intermolecular Regio- and Enantioselective Hydrosilylation of Alkenes with Prochiral Silanes. [PDF]
Zhu XY +5 more
europepmc +1 more source
Base-Catalyzed Remote Hydrogermylation of Olefins. [PDF]
Ahrweiler E, Selmani A, Schoenebeck F.
europepmc +1 more source
Direct vicinal halo-nitration of unsaturated compounds: an overview. [PDF]
Azizi Z +8 more
europepmc +1 more source
Unlocking the Aromatic Profile of Wild-Grown Croatian Fennel: A Comparative Study of Essential Oils and Hydrolates. [PDF]
Vučak A +5 more
europepmc +1 more source
Dose-dependent protective profile of trans-anethole in experimental traumatic brain injury in mice via modulation of apoptotic and inflammatory protein expression, and oxidative stress. [PDF]
Çevik A +5 more
europepmc +1 more source
1,2-Migratory ring expansion of a BN-naphthalene.
Mediavilla BA, Siegler MA, Klausen RS.
europepmc +1 more source
We report here a deallylative β-acylalkylation reaction of allylbenzene derivatives with allyl alcohols in the presence of Cp*Rh catalysts. Allylbenzenes possessing pyridyl and pyrazolyl directing groups were converted to β-aryl ketones via the cleavage of C(aryl)-C(allyl) bonds.
Takuya Kochi, Fumitoshi Kakiuchi
exaly +4 more sources
Synthesis of Allylbenzene Derivatives through sp3 C–H Bond Functionalization of Toluene Derivatives
An sp3 C–H bond-transformation reaction of toluene substrates to afford the corresponding allylbenzene derivatives is described. Optimum conditions were identified as involving the use of tetrabutylammonium iodide and tert-butyl hydroperoxide at 80 °C.
Alireza Abbasi +1 more
exaly +3 more sources
Regioselective Cp*Ir(III)-Catalyzed Allylic C–H Sulfamidation of Allylbenzene Derivatives
In this study we report the development of the regioselective Cp*Ir(III)-catalyzed allylic C-H sulfamidation of allylbenzene derivatives, using azides as the nitrogen source. The reaction putatively proceeds through a Cp*Ir(III)-π-allyl intermediate and demonstrates exclusive regioselectivity for the branched position of the π-allyl.
Simon B Blakey +2 more
exaly +4 more sources
AbstractWe describe a highly diastereoselective approach to anti‐homoallylic alcohols from allylbenzene derivatives and aldehydes. The strategy is based on a cross‐metathesis/isomerization/allylboration sequence catalyzed successively by ruthenium and iridium.
Hemelaere, Rémy +2 more
core +4 more sources

