One-Pot Synthesis of 5,6-Dihydro-4H-1,2-Oxazines by Cyclization of Ketoximes with Derivatives of Allylbenzene [PDF]
A new series of 5,6-dihydro-4H-1,2-oxazines were synthesized via hetero Diels-Alder reaction of α-nitrosolefins with derivatives of allylbenzene. α-Nitrosoolefins were generated from ketoximes by the action of chloramine-T and triethylamine.
P. T. Sowmya +3 more
openaire +3 more sources
Mechanochemical Piezoelectric Catalysis: Advancing the Hydrogenation of Alkenes. [PDF]
This study presents mechanochemical piezoelectric catalysis for alkene hydrogenation, eliminating the need for transition metals, H2, and solvents. The method effectively hydrogenates diverse activated and unactivated alkenes and shows potential for modifying bioactive molecules in pharmaceuticals.
Ai Z +5 more
europepmc +2 more sources
Isolation, Characterization and Antibacterial Activity of 4-Allylbenzene-1,2-diol from Piper austrosinense. [PDF]
Isolation for antibacterial compounds from natural plants is a promising approach to develop new pesticides. In this study, two compounds were obtained from the Chinese endemic plant Piper austrosinense using bioassay-guided fractionation.
Gu M +6 more
europepmc +2 more sources
Allylbenzenes (apiol, dillapiol, myristicin and allyltetramethoxybenzene) are individual components of plant essential oils that demonstrate antitumor activity, as well as enhancing effect on cytotoxic drugs such as paclitaxel, doxorubicin, cisplatin, etc.
Igor D. Zlotnikov +4 more
openaire +1 more source
Wagner-Meerwien rearrangement of allylbenzene derivatives. I. Bromination of safrole.
The reaction of safrole (I) with bromine (II) was examined giving different results from the literature, i.e., 2, 3-dibromo-1-(3', 4'-methylenedioxyphenyl) propane (III), 1, 3-dibromo-2-(3', 4'-methylenedioxyphenyl) propane (V) and their bromo-substituted derivatives (IV and VI) were obtained.
IRINO, TAEKO, OTSUKI, KAZUO
openaire +2 more sources
Contra-Thermodynamic Chain-Walking Isomerization: A Sustainable Tool for Selective Molecular Editing in Green Chemistry. [PDF]
Contra‐thermodynamic chain‐walking isomerization enables selective migration of alkenes to less stable yet synthetically valuable terminal position under mild, catalytic conditions. By integrating tailored metal catalysis, photochemical, and redox strategies, this approach affords efficient access to terminal and remote functionalized products with ...
Turczel G +3 more
europepmc +2 more sources
Characterization of Water/Sucrose Laurate/n-Propanol/ Allylbenzene Microemulsions [PDF]
Water/n-propanol/sucrose laurate/allylbenzene micellar systems were formulated and applied in the isomerization of allylbenzene in the presence of heterogenized derivatives of some platinum group catalysts.
Schwarze, Michael +7 more
core +2 more sources
Di-π-Methan-Umlagerungen von methylsubstituierten Allylbenzolen
Allylbenzene (3) and its derivatives bearing methyl groups at the aromatic ring or at C(1') of the allyl chain (see scheme 1-3, and 6) can cleanly be transformed into the corresponding cyclopropylbenzenes via a triplet di-π-methane rearrangement when ...
Jean-Pierre Fasel, Hans-Jürgen Hansen
doaj +1 more source
Characterization of Odorous and Potentially Harmful Substances in Artists' Acrylic Paint
Acrylic paints are fast drying water based paints that are easy to handle and have a high covering capacity and therefore possess many characteristics that make them applicable in a wide range of applications, such as varnishes or artists paints.
Patrick Bauer +3 more
doaj +1 more source
Catalytic Activity of Cellulose-Supported Platinum and Palladium Nanoparticles for Allylbenzene Hydrogenation [PDF]
Riny Y Parapat +2 more
exaly +2 more sources

