Results 41 to 50 of about 1,240 (135)

Asymmetric azidohydroxylation of styrene derivatives mediated by a biomimetic styrene monooxygenase enzymatic cascade [PDF]

open access: yes, 2021
Enantioenriched azido alcohols are precursors for valuable chiral aziridines and 1,2-amino alcohols, however their chiral substituted analogues are difficult to access. We established a cascade for the asymmetric azidohydroxylation of styrene derivatives
Franssen, Maurice C. R.   +6 more
core   +1 more source

Variability in the Content of Essential Oils and Selected Mycotoxins in Spices of the Apiaceae Family

open access: yesFlavour and Fragrance Journal, Volume 41, Issue 1, Page 37-49, January 2026.
The study analysed essential oils and mycotoxins in five types of spices. The results showed variability in oil yield and detection of T‐2 and HT‐2 toxin concentrations, highlighting the importance of quality assessment of spices to ensure food safety.
Helena Pluháčková   +6 more
wiley   +1 more source

Electrochemical Trifluoromethylchlorosulfonylation of Alkenes via Copper‐Mediated SO2Cl Radical Transfer

open access: yesAdvanced Synthesis &Catalysis, Volume 367, Issue 24, December 22, 2025.
This article reports an electrosynthetic method for vicinal trifluoromethylchlorosulfonylation of alkenes using [Cu(MeCN)4]PF6 and triethylamine, without elaborate ligands. The reaction efficiently adds CF3 and SO2Cl across diverse unactivated alkenes with broad functional group tolerance.
Sachini Rodrigo   +2 more
wiley   +1 more source

Attempts Towards Total synthesis of (±) Spirooliganone-A [PDF]

open access: yes, 2015
The group has recently reported a novel protocol of oxidative dearomatization of napthols using phenyl selenium bromide (PhSeBr). The progress through this process towards the natural product synthesis especially the Spiroliganone system in the different
Bhattacharjya , Punarbasu
core  

Catalysis with Cycloruthenated Complexes† [PDF]

open access: yes, 2022
Cycloruthenated complexes have been studied extensively over the last few decades. Many accounts of their synthesis, characterisation, and catalytic activity in a wide variety of transformations have been reported to date.
Domingo Legarda, Pablo   +4 more
core   +2 more sources

Use of Physiologically Based Biokinetic (PBBK) Modeling to Study Estragole Bioactivation and Detoxification in Humans as Compared with Male Rats [PDF]

open access: yes, 2017
The extent of bioactivation of the herbal constituent estragole to its ultimate carcinogenic metabolite 1′-sulfooxyestragole depends on the relative levels of bioactivation and detoxification pathways.
Bladeren, Peter J. van   +8 more
core  

Integrating Visible‐Light Photocatalysis and Enzymes for the Stereoselective Synthesis of Alcohols and Amines

open access: yesAdvanced Synthesis &Catalysis, Volume 367, Issue 15, August 26, 2025.
The integration between visible‐light photocatalysis and biocatalysis has the potential to greatly improve modern organic synthesis by combining the production of valuable synthetic intermediates under mild photochemical conditions with the high degree of stereoselectivity reached by enzymes. The review collects the recent efforts in the photoenzymatic
Stefano Parisotto, Cristina Prandi
wiley   +1 more source

Chemo-, Diastero-, and Regioselective C−c and C−o Bond formation via Transition Metal Catalysis [PDF]

open access: yes, 2015
The efficient stereoselective formation of C−C and C−O bonds remains a critical challenge in organic chemistry. The level difficulty of these bond formations increases dramatically when regio-, diastereo-, and chemoselectivity issues are present.
Hussain, Nusrah
core   +1 more source

Characterization of Water/Sucrose Laurate/n-Propanol/ Allylbenzene Microemulsions [PDF]

open access: yes, 2012
Water/n-propanol/sucrose laurate/allylbenzene micellar systems were formulated and applied in the isomerization of allylbenzene in the presence of heterogenized derivatives of some platinum group catalysts.
Ayad, Ziad   +7 more
core  

Stereoselective Olefin Metathesis Processes Using Cyclometalated Ruthenium Alkylidene Complexes [PDF]

open access: yes, 2017
The recent development of a class of Z-selective ruthenium metathesis catalysts containing a crucial cyclometalated N-heterocyclic carbene (NHC) ligand has extended the applicability of ruthenium-mediated olefin metathesis to the production of a variety ...
Rosebrugh, Lauren Estelle
core   +1 more source

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