A set of Z‐stereoretentive olefin metathesis catalysts was tested in the synthesis of a pheromone of rice yellow stem borer (Scirpophaga incertulas)—one of the major rice pests in Asia. ABSTRACT Stereoselective olefin metathesis offers access to geometrically well‐defined C–C double bonds and is considered a promising new method for transforming plant ...
Maryana Nadirova +5 more
wiley +1 more source
A Very Readily Prepared Ligand for Rhodium Catalyzed Propene Hydroformylation
Recent developments aimed at switching the selectivity of rhodium catalyzed hydroformylation from a linear‐selective to a branched selective reaction feature ligands that are relatively complicated to prepare. A new ligand, EasyDiPhos, can be made in just one synthetic step and gives unusually low n:iso ratios, i.e., favoring the branched aldehyde, iso‐
José A. Fuentes +4 more
wiley +1 more source
Palladium(II)-Catalysed Oxidation of Alkenes [PDF]
This review provides a summary of recent developments in the palladium(II)-catalysed oxidation of alkenes, focusing largely on reactions which lead to the formation of new carbon–oxygen or carbon–nitrogen bonds.
Benhamou, L, Mann, SE, Sheppard, TD
core +2 more sources
Coordinatively unsaturated ruthenium(II) hydride complex, RuHCl(CO)(PPh3), has been synthetized showing high efficiency in C═C isomerization of terminal alkenes at room temperature and low catalyst loadings. The double bond isomerization of alfa olefins plays a key role in converting plastic waste into propylene via isomerization metathesis (ISOMET ...
Eszter Ábrahám +11 more
wiley +1 more source
Polymer-supported organometallic compounds of titanium and niobium and their applications to catalysis [PDF]
Thesis (Ph.D.) - Michigan State University.
Lau, Chak-po, 1950-
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Study of Synthesis of Ethyl-2-(4-Allyl-2-Methoxyphenoxy)Acetate in Polar Aprotic Solvents [PDF]
Eugenol, a phenol-derived aromatic allylbenzene compound, exhibits a wide spectrum of biological activities (antifungal, antibacterial, antioxidant, analgesic, and antiseptic) and is an active ingredient in various hygiene products.
Agustin, Lela +5 more
core +2 more sources
The development and application of new methods for the synthesis of organozinc carbenoids [PDF]
This thesis concerns the generation of organozinc carbenoids and their subsequent reactions, particularly with alkenes to generate cyclopropanes. The thesis is divided into three major sections. The first section comprises a review of the current methods
Popkin, Matthew Edward
core
Artemisia dracunculus L. (tarragon): a critical review of its traditional use, chemical composition, pharmacology, and safety. [PDF]
Artemisia dracunculus L. (tarragon) has a long history of use as a spice and remedy. Two well-described "cultivars" (Russian and French) are used widely and differ in ploidy level, morphology, and chemistry.
Feistel, B +4 more
core
An experimental investigation of the effects of \u3ci\u3en\u3c/i\u3e-decane on the supercritical pyrolysis of toluene [PDF]
Future and current high-speed jet aircraft will require their fuels to act as the primary coolants as well as propellants. Fuels will be exposed to severe temperatures and pressures in hypersonic aircraft, up to 700°C and 130 atm, respectively ...
Grubb, Catherine A
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Mechanistic Insights and Theory-Assisted Catalyst Development toward Kinetically E-Selective Olefin Metathesis [PDF]
Olefinmetatese, en omordning av C=C-bindinger, har blitt en allsidig metodologi for å konstruere molekylære karbonrammer de siste 30 årene De fleste katalysatorene fokuserer på å konvertere lett tilgjengelige 1-alkener til disubstituerte, interne ...
Reim, Immanuel Albrecht Manfred
core +1 more source

