Results 111 to 120 of about 79,537 (266)

Covalent Functionalization of 2D Semiconductors: A Roadmap to Advanced Electronic Devices

open access: yesAdvanced Functional Materials, EarlyView.
This Review presents recent advances in the covalent functionalization strategies for two‐dimensional semiconductors and their implementation in modern technologies. Layered materials are modified through diverse molecular chemistries (e.g., thiols, diazonium salts, alkyl halides, and electron‐deficient species) to tailor their surface properties ...
Ramiro Quirós‐Ovies   +2 more
wiley   +1 more source

Macrocyclic Aromatic Oligoamides with Diphenyladamantane Units: Conformational Change from Folded to Open by N-Alkyl Removal

open access: yesMolecules
Macrocyclic aromatic amide oligomers of various sizes containing tertiary amides and diphenyladamantane moieties were synthesized by condensation reactions using PhP3Cl2 or LiHMDS.
Sae Maeda   +6 more
doaj   +1 more source

Étude cinétique de l'hydrolyse des amides. XVI. Constantes d'acidité d'ions amidoniums conjugués aux amides aromatiques

open access: yes, 1972
Bruylants Albert, Rysman de Lockerente S., Van Brandt Paul. Étude cinétique de l'hydrolyse des amides. XVI. Constantes d'acidité d'ions amidoniums conjugués aux amides aromatiques. In: Bulletin de la Classe des sciences, tome 58, 1972. pp.
Van Brandt, Paul   +5 more
core   +1 more source

Protein‐Nanoarchitectures for Low‐Field Intracellular Electro‐Immunomodulation

open access: yesAdvanced Functional Materials, EarlyView.
DHQ‐SDH‐mediated binding of AuNPs drives the formation of interconnected, chain‐like nanoarchitectures with enhanced electrical conductivity. These conductive assemblies undergo macrophage uptake and enable low‐field electrical stimulation, promoting M1‐to‐M2 phenotypic switching with decreased iNOS and increased CD206 expression. Such protein‐mediated
Viktoriya Pakharenko   +7 more
wiley   +1 more source

Enabling Nickel‐Catalyzed Suzuki–Miyaura Cross‐Coupling of Carbamoyl Fluorides: Mechanism and Scope

open access: yesChemistryEurope
The first Ni‐catalyzed Suzuki cross‐coupling amide synthesis using stable carbamoyl fluoride starting materials under mild conditions is reported. Mechanistic studies are carried out to document the reactivity of nickel toward the CF bond oxidative ...
Lulu Han   +8 more
doaj   +1 more source

Low antiplasmodial activity of alkaloids and amides from the stem bark of Zanthoxylum rubescens (Rutaceae)

open access: yesParasite, 2007
The stem bark of Zanthoxylum rubescens (syn. Fagara rubescens) is used for treating fevers associated with malaria in the Ivory Coast. Three alkaloids: N-nornitidine, 7,9-dimethoxy-2,3- methylenedioxybenzophenanthridine, and bis[6-(5,6 ...
Penali L.   +4 more
doaj   +1 more source

Bioinspired Hydrogels with Broadly Programmable Mechanics for Soft‐Tissue Interfaces

open access: yesAdvanced Functional Materials, EarlyView.
Sea cucumber‐inspired gelatin hydrogels are formed by directional freezing and mechanically programmed through subsequent ionic treatment. Multiscale characterization and modeling link ion‐regulated chain interactions to directional load transfer within the aligned hierarchical architecture.
Youchao Teng   +20 more
wiley   +1 more source

Unique Role of Microstructure of a Bioimplant Zinc Alloy and Protein Content of Simulated Body Fluid in Corrosion and Fracture

open access: yesAdvanced Functional Materials, EarlyView.
BSA addition to physiological solutions enhances resistance of a Zn alloy to stress corrosion cracking (SCC) but reduces its corrosion resistance. Extended surface characterization explains the contrasting influences on corrosion and SCC. Unexpectedly, the alloy suffers transgranular SCC (TGSCC), despite extensive grain boundary precipitation. Thorough
RK Singh Raman   +9 more
wiley   +1 more source

Direct synthesis of N-trifluoromethyl amides via photocatalytic trifluoromethylamidation

open access: yesNature Communications
N-CF3 amides are promising targets for pharmaceutical and agrochemistry. Unfortunately, there is a defluorination problem of N-CF3 amine starting materials when using common amide bond formation method.
Ru Zhong Zhang   +3 more
doaj   +1 more source

A Review on the Use of Deep Eutectic Solvents in Protection Reactions

open access: yesMolecules
Given the recent research on the application of eco-sustainable methods in organic chemistry, we have focused our attention on the derivatization processes for fundamental functional groups in organic chemistry, such as amino, hydroxyl and carbonyl ...
Rosa Scarpelli   +5 more
doaj   +1 more source

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