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Mono/Dual Amination of Phenols with Amines in Water
Organic Letters, 2020We herein describe a practical direct amination of phenols through a palladium-catalyzed hydrogen-transfer-mediated activation method to synthesize the secondary and tertiary amines. In this conversion, environmentally friendly water and inexpensive ammonium formate were used as solvent and reductant, respectively.
Wanyi Liang +7 more
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2020
Biogenic amines (BAs) are among the most common nitrogenous compounds, widely present in plants, microbes and animal cells. Although BAs play an important role in regulating a number of important biological functions in the human body, overuse of certain bases can cause serious toxicological effects.
A. Kabir +6 more
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Biogenic amines (BAs) are among the most common nitrogenous compounds, widely present in plants, microbes and animal cells. Although BAs play an important role in regulating a number of important biological functions in the human body, overuse of certain bases can cause serious toxicological effects.
A. Kabir +6 more
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Biochemical Pharmacology, 1973
Publisher Summary This chapter discusses amines in schizophrenia. Effects of phenothiazines upon brain catecholamines would be relevant to schizophrenia only if the phenothiazine drugs exerted a selective antischizophrenic action, so that their primary site of action might be assumed to play a prominent role in brain dysfunction in schizophrenia ...
SOLOMON H. SNYDER, SHAILESH P. BANERJEE
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Publisher Summary This chapter discusses amines in schizophrenia. Effects of phenothiazines upon brain catecholamines would be relevant to schizophrenia only if the phenothiazine drugs exerted a selective antischizophrenic action, so that their primary site of action might be assumed to play a prominent role in brain dysfunction in schizophrenia ...
SOLOMON H. SNYDER, SHAILESH P. BANERJEE
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Amine–Amine Exchange in Aminium–Methanesulfonate Aerosols
The Journal of Physical Chemistry C, 2014Aerosol particles are ubiquitous in the atmosphere and have been shown to impact the Earth’s climate, reduce visibility, and adversely affect human health. Modeling the evolution of aerosol systems requires an understanding of the species and mechanisms involved in particle growth, including the complex interactions between particle- and gas-phase ...
Matthew L. Dawson +7 more
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Catalytic CH Amination with Aromatic Amines
Angewandte Chemie, 2012Aniline joins the club: A β-diketiminato copper(I) catalyst enables C-H amination of anilines employing low catalyst loadings to preclude oxidation to the diazene ArN=NAr. Electron-poor anilines are particularly resistant towards diazene formation and participate in the amination of strong and unactivated C-H bonds. N-alkyl anilines also take part in C-
Raymond T, Gephart +5 more
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Development of an Amine Dehydrogenase for Synthesis of Chiral Amines
Angewandte Chemie International Edition, 2012A leucine dehydrogenase has been successfully altered through several rounds of protein engineering to an enantioselective amine dehydrogenase. Instead of the wild-type α-keto acid, the new amine dehydrogenase now accepts the analogous ketone, methyl isobutyl ketone (MIBK), which corresponds to exchange of the carboxy group by a methyl group to produce
Michael J, Abrahamson +4 more
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Amination of 5-azacinnoline with aromatic amines
Chemistry of Heterocyclic Compounds, 1978The 5-azacinnoline molecule was subjected to quantum-mechanical calculation by the Huckel method. The formation of 4-amino derivatives in the case of the reaction of 5-azacinnoline with aliphatic amines in the presence of an oxidizing agent and of 4,4′-bis(5-azacinnolinyl) in the case of dimerization in an oxygenfree medium was substantiated ...
M. F. Budyka +2 more
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NeuroToxicology, 2004
The physiological function in living organisms of amine oxidases, is not completely established but is certainly related to the biogenic amines metabolism and therefore involved in essential processes such as the cell growth and differentiation. A correlation between degree of tumor malignancy and level of AO activity has been reported.
PIETRANGELI, Paola, MONDOVI', Bruno
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The physiological function in living organisms of amine oxidases, is not completely established but is certainly related to the biogenic amines metabolism and therefore involved in essential processes such as the cell growth and differentiation. A correlation between degree of tumor malignancy and level of AO activity has been reported.
PIETRANGELI, Paola, MONDOVI', Bruno
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Synthesis of aminals and aminal-acetals of ?-dimethylaminopolyenals
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1983Aminoformylation of alkoxyacetals affords polymethine salts, treatment of which with CH3OK givesω-dimethylaminopolyenal aminals and aminal-acetals with 2–4 double bonds.
Zh. A. Krasnaya, T. S. Stytsenko
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Regioselective Amination of 3-Bromoindolylmaleimide with Amines
Letters in Organic Chemistry, 2010Title compounds (I) are subjected to the regioselective amination with amines (II) to provide maleimide derivatives (III) or (IV) depending on the amount of (II) and the conditions used.
Di-Fa Jiang +3 more
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