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Monodentate imido and bidentate aminophenolate coordination of 2-aminophenol in rhenium(V) complexes
Journal of Coordination Chemistry, 2006Reactions of trans-[ReOCl3(PPh3)2] and trans-[ReO(OEt)I2(PPh3)2] with 2-aminophenol (H2ap) in acetonitrile led to the formation of cis-[ReOCl2(Hap)(PPh3)] (1) and trans-[Re(ap)(Hap)I(PPh3)2]I (2), respectively. The X-ray crystal structures show that Hap is coordinated as a bidentate chelate via the neutral amino nitrogen and deprotonated phenolate ...
T. I. A. Gerber, D. Luzipo, P. Mayer
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Nature, 1953
A SINGLE crystal of meta-aminophenol was previously studied1 by means of rotation photographs only, whereby the identification of spots remains doubtful. We used the Weissenberg method and identified the spots by the method of Schneider2. We also studied the optical properties of this crystal.
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A SINGLE crystal of meta-aminophenol was previously studied1 by means of rotation photographs only, whereby the identification of spots remains doubtful. We used the Weissenberg method and identified the spots by the method of Schneider2. We also studied the optical properties of this crystal.
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Metabolism of para-Aminophenol by Rat Hepatocytes
Drug Metabolism and Disposition, 2000Autoxidation of para-aminophenol (PAP) has been proposed to account for the selective nephrotoxicity of this compound. However, other studies suggest that hepatic metabolites of PAP rather than the parent compound may be responsible for renal damage. These studies were designed to investigate PAP metabolism in isolated hepatocytes.
Z, Yan +3 more
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Extradiol cleavage of o-aminophenol by pyrocatechase
Biochemical and Biophysical Research Communications, 1978Abstract o-Aminophenol is cleaved by the intradiol dioxygenase, pyrocatechase, in an extradiol manner to give picolinic acid as the major product. Inhibition of o-aminophenol cleavage with various reagents was comparable to that observed for catechol cleavage, indicating that both reactions are catalyzed by the same enzyme.
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Theoretical studies on electrochemistry of p-aminophenol
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2007Geometric parameters, vibrational frequencies and thermochemical values of p-quinonimine (p-Q) and p-aminophenol (p-AP) were computed by ab initio calculation (HF) and density function theory (DFT) with the 6-31G(d,p) basis set. Cyclic voltammetry with a goldren electrode of p-AP solutions in phosphate buffers at pH 7.30 showed that standard electrode ...
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The enzymic oxidation of o-aminophenols
Biochimica et Biophysica Acta, 1958H T, NAGASAWA, M A, MORGAN, H R, GUTMANN
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