Results 21 to 30 of about 1,790 (186)

T‐Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond

open access: yesAngewandte Chemie, EarlyView.
A cationic, structurally constrained stibenium platform mediates anti‐Markovnikov hydrostibination of alkenes via element–ligand cooperativity (ELC), thereby bypassing the need for weak Sb─H bonds. ABSTRACT The hydrostibination of alkenes represents a largely underdeveloped transformation, owing to the intrinsic lability of the required Sb─H reagents ...
Ekta Nag   +4 more
wiley   +2 more sources

The transformations of thiols and their dimers in the redox-mediated thiol-disulfide exchange reaction

open access: yesChimica Techno Acta, 2023
A search for new approaches to sulfurous waste utilization is one of the urgent tasks of chemical technology. Thiol-disulfide exchange reaction (TDE) is one of the possible ways to involve technogenic wastes in organic synthesis.
Daria A. Burmistrova   +2 more
doaj   +1 more source

Catalytic condensation for the formation of polycyclic heteroaromatic compounds

open access: yesNature Communications, 2018
The development of novel chemical reactions converting biomass-derived alcohols into important classes of compounds is a particularly attractive strategy.
Daniel Forberg   +2 more
doaj   +1 more source

Bacterial degradation of monocyclic aromatic amines

open access: yesFrontiers in Microbiology, 2015
Aromatic amines are an important group of industrial chemicals, which are widely used for manufacturing of dyes, pesticides, drugs, pigments, and other industrial products.
Pankaj Kumar Arora
doaj   +1 more source

Surface acoustic wave nebulization improves compound selectivity of low-temperature plasma ionization for mass spectrometry

open access: yesScientific Reports, 2021
Mass spectrometry coupled to low-temperature plasma ionization (LTPI) allows for immediate and easy analysis of compounds from the surface of a sample at ambient conditions.
Andreas Kiontke   +5 more
doaj   +1 more source

Determination of ionization constants for some aromatic Schiff base acids derived from a benzyl compound with aromatic amines [PDF]

open access: yesمجلة التربية والعلم, 2006
The paper is concerned with the preparation and determination o'f pKa for four acidic Schiff bases from the reaction of benzil with other appropriate aromatic primary amines as o,m,p-aminophenols and 4-amino-2-hydroxybenzoic acid.
Adel Azzoz   +2 more
doaj   +1 more source

o-Aminophenol in Experimental Tuberculosis [PDF]

open access: yesNature, 1952
IN 1948 Okamoto1 reported that o-aminophenol showed a tuberculostatic effect both in vitro and in vivo (in guinea pigs). He also referred to favourable progress when this drug was used clinically in pulmonary tuberculosis. In the course of a study of the chemotherapy of experimental tuberculosis, we have included o-aminophenol in our tests.
openaire   +2 more sources

Cationic cobalt-catalyzed [1,3]-rearrangement of N-alkoxycarbonyloxyanilines

open access: yesBeilstein Journal of Organic Chemistry, 2018
A cationic cobalt catalyst efficiently promoted the reaction of N-alkoxycarbonyloxyanilines at 30 °C, affording the corresponding ortho-aminophenols in good to high yields.
Itaru Nakamura   +3 more
doaj   +1 more source

QSAR Assessing the Efficiency of Antioxidants in the Termination of Radical-Chain Oxidation Processes of Organic Compounds

open access: yesMolecules, 2021
Using the GUSAR 2013 program, the quantitative structure–antioxidant activity relationship has been studied for 74 phenols, aminophenols, aromatic amines and uracils having lgk7 = 0.01–6.65 (where k7 is the rate constant for the reaction of antioxidants ...
Veronika Khairullina   +4 more
doaj   +1 more source

Chiral Plasmonic Printing of Discrete Hierarchical Chiral Au@Chiral Ag Semi‐Core‐Shell Nanorods With Chiral Plasmon‐Enhanced Photocatalysis

open access: yesAdvanced Science, EarlyView.
Chiral plasmonic printing uses CPL as a chiral stimulus to guide asymmetric Ag deposition on chiral Au NRs seeds. Under CPL, hot carriers reduce Ag+, and the process is controlled by both the CPL handedness and the chiral SPR. L‐dc Au generates more hot electrons under LCP than RCP, while D‐dc Au shows the opposite, revealing chiral photon‐selective ...
Yaxin Cao   +6 more
wiley   +1 more source

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