Results 51 to 60 of about 1,774 (180)

Ligand‐Level Chemical Activation: Coordination with Benefits

European Journal of Inorganic Chemistry, EarlyView.
While often perceived as a liability, ligand‐based reactivity in carefully designed settings becomes a powerful synthetic tool. The key to streamlined processes overriding classical ionic reactivity is the selective electron redistribution induced by metal coordination. This enables storage of electrons and protons or incorporation of functional groups
Oscar Charpentier, Agnideep Das, Marine Desage‐El Murr   +2 more
wiley   +1 more source

Spatial variability and atmospheric levels of phenolic compounds measured by passive samplers in the Strasbourg metropolitan area

Environment International
Phenolic compounds are ubiquitous atmospheric pollutants mainly emitted by biomass burning, industrial activities and vehicular exhaust. In the current study, we quantified 54 phenols at six sites in the Strasbourg metropolitan area, classified into ...
Dani Khoury, Supansa Chimjarn, Olivier Delhomme, Maurice Millet   +3 more
doaj   +1 more source

Merging Biocatalysis and Chemocatalysis in Flow: State‐of‐the‐Art and Future Directions for Sustainable Synthesis

Angewandte Chemie, Volume 138, Issue 25, 15 June 2026.
This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis, Matteo Damian, Francesco G. Mutti   +2 more
wiley   +2 more sources

Fast Nonradiative Decay in o-Aminophenol [PDF]

The Journal of Physical Chemistry A, 2014
The gas phase structure of 2-aminophenol has been investigated using UV-UV as well as IR-UV hole burning spectroscopy. The presence of a free OH vibration in the IR spectrum rules out the contribution of the cis isomer, which is expected to have an intramolecular H-bond, to the spectra. The excited state lifetimes of different vibronic levels have been
C. Capello, Marcela, Broquier, Michel, Ishiuchi, Shun-Ichi, Y. Sohn, Woon, Fujii, Masaaki, Dedonder-Lardeux, Claude, Jouvet, Christophe, A. Pino, Gustavo   +7 more
openaire   +5 more sources

A Prodrug Approach for Activity‐Based Chemical Modulation toward Multiple Pathological Targets in Alzheimer's Disease

Small, EarlyView.
We present a pathology‐responsive, activity‐based prodrug strategy that tackles multiple hallmarks of Alzheimer's disease (AD). Rationally designed BE compounds convert under oxidative stress into redox‐active aminophenols, neutralizing ROS and redirecting both metal‐free and metal‐bound Aβ aggregation.
Jimin Lee, Eunseo Hong, Chanju Na, Yan Li, Jun Go, Ju‐Eun Kim, Hyun‐Hee Seo, Jong‐Min Suh, Jimin Kwak, Young‐Ho Lee, Kyoung‐Shim Kim, Chul‐Ho Lee, Mingeun Kim, Mi Hee Lim   +13 more
wiley   +1 more source

DNA‐Enzyme Hybrid Nanostructures: Functional Materials to Modulate Enzymatic Activity

Small, EarlyView.
DNA–enzyme hybrid nanostructures enable precise spatial and stoichiometric control over enzyme organization, offering a powerful platform to modulate catalytic activity. This review critically evaluates key mechanistic hypotheses, including proximity effects, microenvironment changes, confinement, and stabilization, as well as highlighting ...
Manar Elnaggar, Amelie Heuer‐Jungemann
wiley   +1 more source

A novel water‐soluble near‐infrared fluorescent probe for monitoring viscosity fluctuations in plants and zebrafish under abiotic stresses

Smart Molecules, EarlyView.
HJA‐MQ‐D exhibits a rapid and sensitive response to viscosity changes based on the twisted intramolecular charge transfer mechanism. Displaying near‐infrared emission and excellent water‐solubility, enabling imaging at the cellular and whole plant level.
Yixue Feng, Keke Ding, Yongxu Yang, Quanliang Liu, Silin Xu, Chunhui Liu, Zhihong Xu, Xufeng Hou, Jihong Huang, Tony D. James   +9 more
wiley   +1 more source

A case of canine urothelial carcinoma of the urinary bladder with skull and skeletal metastases

Australian Veterinary Journal, EarlyView.
Canine urinary bladder neoplasia is uncommon, representing less than 1% of canine neoplasms. Amongst cases of urinary bladder neoplasia in dogs, primary urothelial carcinoma is the most frequent. Urothelial carcinomas are malignant invasive tumours which tend to be slow growing and metastasise late.
A Teh, T Sima, E Shinozaki, R Malik
wiley   +1 more source

Dearomatization of 3-Aminophenols for Synthesis of Spiro[chromane-3,1′-cyclohexane]-2′,4′-dien-6′-ones via Hydride Transfer Strategy-Enabled [5+1] Annulations

Molecules
The Sc(OTf)3-catalyzed dearomative [5+1] annulations between readily available 3-aminophenols and O-alkyl ortho-oxybenzaldehydes were developed for synthesis of spiro[chromane-3,1′-cyclohexane]-2′,4′-dien-6′-ones.
Jia-Cheng Ge, Yufeng Wang, Feng-Wei Guo, Xiangyun Kong, Fangzhi Hu, Shuai-Shuai Li   +5 more
doaj   +1 more source

Glove Reuse Limits in Hair Dyeing: Permeation of p‐Phenylenediamine and Aminophenols Through Natural Rubber Latex and Neoprene After Repeated Washing

Contact Dermatitis, EarlyView.
Disposable glove reuse reduced chemical protection during repeated hair‐dye exposure. Under ASTM F739 testing, natural‐rubber‐latex deteriorated rapidly after one reuse, whereas neoprene performed better initially but also declined over repeated cycles. Wash type had no significant effect. These findings support single‐use only and discourage the reuse
Pei‐Ting Jian, Yu‐Wen Lin
wiley   +1 more source