Results 171 to 180 of about 114,508 (253)

Direct Solar Power‐Driven Durable Ammonia Electrosynthesis From Nitrate Under Fluctuating Voltage Conditions

open access: yesAngewandte Chemie, EarlyView.
Isolated Sn sites on Cu(111) induce a highly asymmetric charge distribution, which promotes water dissociation, accelerates key intermediate hydrogenation, and suppresses competing hydrogen evolution. As a result, SnCu111 delivers NH3 Faradaic efficiencies above 90% over an 800 mV potential window and enables stable direct solar power‐driven NH3 ...
Xiaokang Wang   +8 more
wiley   +2 more sources

Acetylene Semi‐Hydrogenation by Photocatalysis

open access: yesAngewandte Chemie, EarlyView.
Photocatalytic acetylene semi‐hydrogenation is an emerging light‐driven route to polymer‐grade ethylene, offering a mild alternative to energy‐intensive thermocatalysis. By replacing H2 co‐feed with water or other proton sources, these systems can achieve high selectivity under ambient conditions.
Anna Fortunato   +6 more
wiley   +2 more sources

Acceptor‐Doped Cerium Oxides Enabling Metallic Nanocatalyst Exsolution for Hydrogen Production From Ammonia

open access: yesAngewandte Chemie, EarlyView.
Outstanding catalytic results for NH3 decomposition for H2 production were obtained with metallic Ru, Rh, and RuRh nanoparticle‐exsolved CeO2‐based catalysts. Significant lower amounts of available superficial metallic fractions were needed in comparison to conventional Ru‐impregnated materials.
Andrés López‐García   +8 more
wiley   +2 more sources

Biosynthesis and Genetic Tuning of Guanine Crystals via Metabolic Engineering of Yeast

open access: yesAngewandte Chemie, EarlyView.
We demonstrate how yeast cells can be harnessed as cellular factories for the synthesis of optically functional guanine crystals, where genetic editing is used to tune crystal size, order and optical properties. This demonstrates a powerful new biosynthetic approach for the development of sustainable and biocompatible optical pigments, which utilizes ...
Jerome N. Janssen   +11 more
wiley   +2 more sources

Ambiphilic Ligand Stabilization of Aluminum(I) Fragments: Halides, Cations, and a Hydride

open access: yesAngewandte Chemie, EarlyView.
Stabilization of elusive aluminum(I) halides in the framework of an ambiphilic ligand is reported. The unique bonding situation at the trigonal‐bipyramidal aluminum center is analyzed, and the coordination chemistry and Al(I)Br transfer reactivity of the complexes are presented.
Charlotte S. V. Weiß   +1 more
wiley   +2 more sources

Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective

open access: yesAngewandte Chemie, EarlyView.
Ionic liquids (ILs) have gained great attention as safe electrolyte components in recent years. This review elucidates the temperature effects on IL‐based electrolytes from molecular configurations, physicochemical properties, and interfacial chemistry, raises the challenges and design strategies operating at low‐ and HT, providing valuable guidance ...
En Xie   +11 more
wiley   +2 more sources

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