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Sustainable electrochemical synthesis of aliphatic nitro-NNO-azoxy compounds employing ammonium dinitramide and their in vitro evaluation as potential nitric oxide donors and fungicides [PDF]

open access: yesBeilstein Journal of Organic Chemistry
An atom- and step-economical electrochemical method for the synthesis of aliphatic nitro-NNO-azoxy compounds from the corresponding nitroso compounds was developed employing ammonium dinitramide, a prospective green oxidant for aerospace propulsion ...
Alexander S. Budnikov   +8 more
doaj   +3 more sources

Exploring the Mechanism of Ammonium Dinitramide Synthesis through DFT Calculations [PDF]

open access: yesACS Omega
Ammonium dinitramide (ADN) has emerged as a promising substitute for ammonium perchlorate (AP) in solid rocket propellants due to its favorable energetic properties and absence of halogens.
Letícia M. S. V. Queiroz   +4 more
doaj   +3 more sources

Ammonium Dinitramide as a Prospective N–NO2 Synthon: Electrochemical Synthesis of Nitro-NNO-Azoxy Compounds from Nitrosoarenes [PDF]

open access: yesMolecules
In this study, the electrochemical coupling of nitrosoarenes with ammonium dinitramide is discovered, leading to the facile construction of the nitro-NNO-azoxy group, which represents an important motif in the design of energetic materials.
Alexander S. Budnikov   +9 more
doaj   +3 more sources

Thermal Behaviors and Interaction Mechanism of Ammonium Dinitramide with Nitrocellulose [PDF]

open access: yesMolecules, 2023
The initial interaction mechanism is very important for the design and safety of nano-scale composite energetic materials composed of ammonium dinitramide (ADN) and nitrocellulose (NC).
Qiong Wang   +5 more
doaj   +2 more sources

Characterization of Electrospinning Prepared Nitrocellulose (NC)-Ammonium Dinitramide (ADN)-Based Composite Fibers [PDF]

open access: yesNanomaterials, 2023
Nanoscale composite energetic materials (CEMs) based on oxidizer and fuel have potential advantages in energy adjustment and regulation through oxygen balance (OB) change.
Qiong Wang   +5 more
doaj   +2 more sources

Transmissive Mode Laser Micro-Ablation Performance of Ammonium Dinitramide-Based Liquid Propellant for Laser Micro-Thruster [PDF]

open access: yesMicromachines, 2023
The transmissive mode laser micro-ablation performance of near-infrared (NIR) dye-optimized ammonium dinitramide (ADN)-based liquid propellant was investigated in laser plasma propulsion using a pulse YAG laser with 5 ns pulse width and 1064 nm ...
Baosheng Du   +7 more
doaj   +2 more sources

Prediction of Ethanol-Mediated Growth Morphology of Ammonium Dinitramide/Pyrazine-1,4-Dioxide Cocrystal at Different Temperatures [PDF]

open access: yesMolecules, 2023
The crystal morphology of high energetic materials plays a crucial role in aspects of their safety performance such as impact sensitivity. In order to reveal the crystal morphology of ammonium dinitramide/pyrazine-1,4-dioxide (ADN/PDO) cocrystal at ...
Yuanping Zhang   +3 more
doaj   +2 more sources

Preparation and growth mechanism of micro spherical ammonium dinitramide crystal based on ultrasound-assisted solvent-antisolvent method [PDF]

open access: yesUltrasonics Sonochemistry, 2021
Micro-sized spherical ammonium dinitramide (ADN) crystals are successfully prepared by a facile ultrasound-assisted solvent-antisolvent recrystallization method without introducing any additives.
Jingjing Li   +6 more
doaj   +2 more sources

Research progress on the catalytic and thermal decomposition of ammonium dinitramide (ADN). [PDF]

open access: yesRSC Adv
Ammonium dinitramide (NH4N(NO3)2, ADN) is regarded as a promising oxidizer due to its low signature and high specific impulse. Generally, ADN undergoes exothermic decomposition above 140 °C accompanied by the byproduct of ammonium nitrate (AN).
Tian Y   +8 more
europepmc   +2 more sources

Thermal Decomposition of Ammonium Dinitramide (ADN) as Green Energy Source for Space Propulsion

open access: yesAerospace, 2023
The thermal decomposition of an ammonium dinitramide-based energetic compound was conducted for the first time using a dispersive inductively coupled plasma mass spectrometer, DTA-TG analysis, and pyrolysis at a constant temperature. A liquid droplet was
Zakaria Harimech   +4 more
doaj   +2 more sources

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