Results 141 to 150 of about 69,365 (292)

Remapping the Synthetic Landscape of α‐Tertiary Alkylamines via Dual‐Functional Catechol

open access: yesAngewandte Chemie, EarlyView.
A three‐component assembly strategy has been developed for the modular synthesis of hindered α‐tertiary aliphatic amines from readily available precursors through unlocking the dual role of catechol. The practicality of this methodology has been demonstrated in over 90 examples, including compounds that are otherwise difficult to access, along with ...
Chen‐Yan Cai, Yuzuru Kanda, Tian Qin
wiley   +2 more sources

Sustainable Pd‐Catalyzed Aminations “on Dirty Water”

open access: yesAngewandte Chemie, EarlyView.
Aminations, done safely yet neat, and therefore, quickly, using low levels of Pd, in “dirty water” that must contain 30% KOH; not NaOH, and not at 5%,10%, 20%, 40%, or 50% KOH. Moreover, no base sensitivity of functional groups! Very cool. Thank you, Nature.
Erfan Oftadeh   +4 more
wiley   +2 more sources

Rapidly Diversifying Hydrogen‐Bonded Organic Frameworks With Permanent Porosity

open access: yesAngewandte Chemie, EarlyView.
This article reviews diversifying hydrogen‐bonded organic frameworks (HOFs) with permanent porosity reported over the past 15 years, based on the molecular structures of their constituent tectons. Furthermore, several distinctive aspects and concepts are described, such as permanent porosity, isostructural (isoreticular) HOFs, and multicomponent mixed ...
Taito Hashimoto, Ichiro Hisaki
wiley   +2 more sources

Light induced electropolymerization of aniline [PDF]

open access: yes, 2005
198-204Electropolymerization of aniline has been carried out in the presence of light. The kinetics of polymer growth has been studied in terms of weight of the aggregate as a function of time in the absence and presence of ZnSO4 and found that zinc ...
Das, Ishwar   +2 more
core  

Accidental severe poisoning with methemoglobinogenic substance: A case report

open access: yesMedycyna Pracy, 2017
A 45-year-old male patient was admitted to the Regional Poison Center because of poisoning with dimethyloaniline contained in a toxic resin-curing dimethyl aniline-based formulation ingested inadvertently. Intoxication happened at workplace.
Kinga Rośniak-Bąk   +3 more
doaj  

The Direct Production of Aniline from Benzene [PDF]

open access: yes, 1927
Aniline was accurately investigated by A. W. Hoffman in 1843. He was able to show that all of the above products are identical and for them he selected Fritsche's name, aniline.
Slaughter, John Robert
core  

Selective flow-injection determination of aniline and m-nitroaniline in mixtures containing isomeric nitroanilines and aniline [PDF]

open access: yes, 1998
Operating conditions for the selective flow-injection determination of aniline and 3-nitroaniline in the presence of isomeric nitroanilines as 5,7-dichloro-4,6-benzofuroxan derivatives of test compounds are determined by varying the flow composition. The
Evgen'ev M.   +3 more
core  

Durch anomere Amide ermöglichte divergente Synthese unsymmetrischer Harnstoffe, Carbamate, Thioester und Amide aus Aldehyden

open access: yesAngewandte Chemie, EarlyView.
Eine divergente Aldehyd‐Funktionalisierungssequenz, ermöglicht durch ein anomeres Amid, erlaubt den Ein‐Topf‐Zugang zu unsymmetrischen Harnstoffen, Carbamaten, Thiocarbamaten, Thioestern und Amiden. Entscheidend für diese Transformation ist die Bildung von N‐Boc‐Hydroxamat‐Intermediaten, die als Plattformen für eine orthogonale Aktivierung über Lossen ...
Jasper L. Tyler   +6 more
wiley   +1 more source

Heterocycle-guided synthesis of m-hetarylanilines via three-component benzannulation

open access: yesBeilstein Journal of Organic Chemistry
A one-pot three-component synthesis of substituted meta-hetarylanilines from heterocycle-substituted 1,3-diketones has been developed. The electron-withdrawing power of the heterocyclic substituent (which can be estimated on the basis of calculated ...
Andrey R. Galeev   +3 more
doaj   +1 more source

Simultaneous removal of Lead and Aniline from industrial wastewater using magnetic composite of Fe3O4/PAC

open access: yesSalāmat-i kār-i Īrān, 2015
Background and aims: Today, using magnetic adsorbents and the subsequent magnetically separation of pollutants is highly considered by researchers due to it’s ease of use, low cost and rapid results. Therefore the aim of this study was the synthesis of a
R Rezaei Kalantary   +6 more
doaj  

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