Results 161 to 170 of about 86,786 (280)

Isolable ArInH2: Double Hydroindation Agent

Chemistry – A European Journal, EarlyView.
Stable crystalline monomeric indium dihydride ArInH2 was isolated and completely characterized using effective support of the P,C,P‐pincer ligand (Ar = 2,6‐(tBu2PO)2C6H3). It serves as unparalleled hydroindation agent, thereby extending the family of known hydrometallation process relying on heavy p‐block metals.
Adam Hochmal, Zdeňka Růžičková, Aleš Růžička, Roman Jambor, Milan Erben, Libor Dostál   +5 more
wiley   +1 more source

Hydrogen Release From Silicon─Hydrogen Systems: From Surface Chemistry to Higher‐Coordinate Molecular Mechanisms

Chemistry – A European Journal, EarlyView.
Hydrogen‐release processes in silicon chemistry occur across a broad spectrum of systems, including crystalline silicon surfaces, nanoporous materials, Zintl phases, and molecular hydrides. This Review highlights how Si─H activation and H2 evolution are governed by structure, coordination environment, and dynamic access to reactive geometries, with ...
Robin Rothfelder, Jonathan O. Bauer
wiley   +1 more source

Synthesis and Reduction of Super‐Bulky Bis(anilido)acridanide Aluminium Complexes

Chemistry – A European Journal, EarlyView.
A new generation of super‐bulky bis(anilido)acridanide ligands has been developed and used in the preparation of aluminium(III) complexes. ABSTRACT Super‐bulky bis(anilido)acridanide pro‐ligands (NNNAr)H3 (NNNAr = 4,5‐bis(anilido)‐2,7,9,9‐tetramethylacridanide, anilido = NAr, Ar = DCHP, 2,6‐dicyclohexylphenyl; TCHP, 2,4,6‐tricyclohexylphenyl) have been
Matthew J. Evans, Joseph M. Parr, Cameron Jones   +2 more
wiley   +1 more source

Two‐Coordinate 13‐Electron PdI Complexes Stabilized by the Bulky DIMeIHeptCl NHC Ligand

Chemistry – A European Journal, EarlyView.
Bulky N‐heterocyclic carbene (NHC) ligand DiMeIHeptCl stabilizes rare two‐coordinate 13‐electron PdI species. These monomeric complexes are directly observed crystallographically and by electron paramagnetic resonance (EPR) spectroscopy, and display unusual structures and radical‐type reactivity, forming Pd0(NHC) via Pd─X bond homolysis or ...
Volodymyr Semeniuchenko, Sepideh Sharif, Neha Rana, Nalin Chandrasoma, Wilfried M. Braje, R. Tom Baker, Jeffrey M. Manthorpe, William J. Pietro, Michael G. Organ   +8 more
wiley   +1 more source

Mechanistic Insights Into Luminol Chemiexcitation: The Role of the Amide Carbonyls

Chemistry – A European Journal, EarlyView.
By means of quantum‐chemical calculations, we demonstrate that the 1,2‐dioxin ring forms following nitrogen release from parent luminol. We also identify alkoxide groups derived from the amide carbonyls of luminol as key enhancers of the chemiexcitation yield.
Juliana Cuéllar‐Zuquin, Héctor Vila‐Cervera, Angelo Giussani, Daniel Roca‐Sanjuán   +3 more
wiley   +1 more source

A designer enzyme for hydrazone and oxime formation featuring an unnatural catalytic aniline residue

Nature Chemistry, 2018
I. Drienovská, C. Mayer, Christopher Dulson, G. Roelfes   +3 more
semanticscholar   +1 more source

Unraveling Synergistic Regulation Mechanism in Nitrogen/Sulfur Co‐Doped Biomass‐Derived Hard Carbon Toward Durable Sodium‐Ion Battery Anodes

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Nitrogen/sulfur co‐doping optimizes the electron and spatial structure of biomass‐derived hard carbon, and the anode demonstrates superior long‐term cycling stability over 2000 cycles, validating an improved “adsorption‐intercalation‐pore filling” mechanism.
Qian Long, Fangyuan Zhang, Jiayu Qu, Songtao Li, Renfei Cheng, Yaning Zhao, Di Guo, Zhengwang Zhu, Haifeng Zhang   +8 more
wiley   +1 more source

Directly Sunlight‐Chargeable Core‐Shell Azobenzene Fabric via Coaxial Electrospinning with Tunable Personal Thermal Management

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This work presents a leakage‐free, sunlight‐chargeable core‐shell Azo‐based textile that effectively bridges molecular photothermal storage with wearable functionality, offering a robust platform for on‐demand solar‐powered personal thermal management.
Yating Zhang, Liqi Dong, Hua Pan, Mo Zhou, Fei Zhai, Zhiping Ye, Wei Feng   +6 more
wiley   +1 more source

Smart Functional Hydrogels: Emerging Platforms for Thermal and Electrochemical Energy Harvesting and Conversion Systems

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The hydrogel exhibits versatile functions, including efficient thermogalvanic conversion under a temperature difference, and acting as a cooling layer/forming a thermally conductive nanoactive composite for thermovoltaic conversion. Additionally, its self‐healing and self‐powered flexibility play a key role in energy storage systems. The growing demand 
Eunah Kang
wiley   +1 more source

1,3‐Bis(tetrylene)s: Emerging Platforms for Functional Main‐Group Molecules

European Journal of Inorganic Chemistry, EarlyView.
Bridge design governs the stability and reactivity of 1,3‐bis(tetrylene)s. This review surveys pnictogen‐, chalcogen‐, and tetrel‐bridged systems and shows how geometric preorganization and electronic communication can enable cooperative bond activation and access to unusual heavy‐element π frameworks. Main‐group chemistry has undergone a resurgence as
Daichi Uchida, Yoshiyuki Mizuhata
wiley   +1 more source