Results 71 to 80 of about 30,335 (240)

Domino Polymerization for the Synthesis of Reductively Degradable Poly(disulfide)s With Arbitrary Side‐Chain Structures

open access: yesAngewandte Chemie, EarlyView.
We developed a novel domino polymerization to synthesize reductively degradable poly(disulfide)s with tunable side chains. A novel monomer bearing thiolactone and pyridyl disulfide groups reacts with various amines, enabling continuous ring‐opening and disulfide exchange.
Yukiya Kitayama   +2 more
wiley   +2 more sources

The ITGB2‐COPS3‐SOX2 Axis and SOX2 Liquid‐Liquid Phase Separation: Dual Mechanisms Governing Osteosarcoma Stemness

open access: yesAdvanced Science, EarlyView.
Osteosarcoma stemness is driven by the ITGB2‐COPS3‐SOX2 signaling axis. This study reveals that nuclear COPS3 stabilizes SOX2, which in turn undergoes liquid‐liquid phase separation to promote stemness. Based on this mechanism, a novel COPS3 inhibitor, Z‐5891, was developed, effectively suppressing tumor growth and stemness in vivo, offering a ...
Lei Guo   +7 more
wiley   +1 more source

Trinuclear Heptamethine Dyes for Shortwave Infrared In Vivo Imaging

open access: yesAngewandte Chemie, EarlyView.
The reactivity of cyclopentenyl‐bridged polymethine dyes is leveraged to synthesize shortwave infrared (SWIR)‐emissive di‐ and trinuclear polymethine dyes. Chromenylium‐ and flavylium‐based trinuclear dyes demonstrate increased nucleophilic stability, minimal aggregation in micelle formulations, and notable lymph node accumulation.
Cesar A. Garcia   +6 more
wiley   +2 more sources

Photochemische Addition von Anilinen an 1,3-Diene

open access: yesCHIMIA, 1979
Anilines, e. g. aniline (12), N-methylaniline (16), 2,6-dimethyl-aniline (14), 2-(2'-butenyl)-N-methylaniline (4) or 2-(2'-cyclo-hexenyl)-N-methylaniline (8) when irradiated with a high pressure mercury lamp in methanol, acetonitrile, benzene or ...
Synèse Jolidon, Hans-Jürgen Hansen
doaj   +1 more source

Review: Insight on Porous Carbon Positive Electrode for Sodium‐Ion Capacitors: Interplay Between Synthesis, Properties, and Performance

open access: yesAdvanced Science, EarlyView.
Sodium ion capacitor (SIC) is currently constrained by the low discharge capacity of commercial activated carbon as positive electrode material. This review provides a holistic summary of research efforts on alternative porous carbon materials for SIC. Image created by the authors with www.biorender.com.
Ademola Adeniji   +2 more
wiley   +1 more source

Semi‐Reduction of Allenes to Access Deuterated Allylic Isotopomers, Isotopologs and Enantioisotopomers

open access: yesAngewandte Chemie, EarlyView.
Modular and Precise Deuteration: The synthesis of molecules precisely deuterated at allylic, vinylic or both positions remains a challenging task. This work discloses a modular semi‐reductive deuteration that enables the synthesis of various isotopologs including precisely labeled d1‐, d2‐, d3‐, d5‐, and d7‐products.
Lihan Qi   +10 more
wiley   +2 more sources

Optimized decolorization of aniline blue dye using potassium ferrate (VI)

open access: yesDesalination and Water Treatment
Aniline blue dye is extensively utilized in the coloration of textiles, paper, and plastics industries. This study explores the decolorization of aniline blue dye using potassium ferrate (VI), focusing on the effects of pH, molar ratio, and temperature ...
Bimo Tri Goutomo   +2 more
doaj   +1 more source

Synthesis and Antimicrobial Activity of Some [1,2,4]-Triazole Derivatives

open access: yesJournal of Chemistry, 2013
A series of novel [1,2,4]-triazolo piperidine (8), [1,2,4]-triazolo piperazine (9a-c), [1,2,4]-triazolo phenylether (10a-e), and [1,2,4]-triazolo aniline (11a-c) derivatives have been synthesized.
Bhimagouda S. Patil   +4 more
doaj   +1 more source

Synthesis of New Azo Compounds Based on N-(4-Hydroxypheneyl)maleimide and N-(4-Methylpheneyl)maleimide

open access: yesMolecules, 2010
Maleic anhydride was reacted with p-aminophenol and p-toluidine in the presence of di-phosphorus pentoxide (P2O5) as a catalyst to produce two compounds: N-(4-hydroxy-phenyl)maleimide (I) and N-(4-methylphenyl)maleimide (II). The new azo compounds I(a-c)
Issam Ahmed Mohammed, Asniza Mustapha
doaj   +1 more source

Aggregation‐Induced Resonance Energy Transfer in Polymer Dots to Boost Electrochemiluminescence Performance for Bioimaging of Glycan on Cells

open access: yesAdvanced Science, EarlyView.
This study pioneers an aggregation‐induced resonance energy transfer mechanism by synergistically integrating aggregation‐induced emission (AIE), resonance energy transfer (RET), and thermally activated delayed fluorescence (TADF) within co‐reactant conjugated polymers to develop self‐enhanced ECL emitters, which achieves an ECL efficiency up to 92.6 ...
Chao Wang   +6 more
wiley   +1 more source

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