Results 91 to 100 of about 1,592,056 (239)

Decouple H2O2 Electrosynthesis From Microenvironmental Decomposition via Atomic Site Density Engineering

open access: yesAngewandte Chemie, EarlyView.
Using defect‐rich Co‐N2O2 single‐atom catalysts as a model system, this work reveals that atomic site density governs the competition between H2O2 electrosynthesis and microenvironmental decomposition during 2e−‐ORR. Optimised site isolation suppresses HPRR and HDR, thereby establishing a site‐density principle to balance H2O2 formation and ...
Junwen Chen   +8 more
wiley   +2 more sources

Water, Alcohols, Amines, and Amides as Formal Hydrogen‐Atom‐Transfer Reagents Through Activation With Redox‐Active Lewis Acids

open access: yesAngewandte Chemie, EarlyView.
Protic molecules containing strong O─H or N─H bonds typically resist hydrogen‐atom abstraction because of the high reactivity of the resulting heteroatom‐centered radicals. However, association of the protic molecules with redox‐active Lewis acids can provide powerful hydrogen‐atom donors or proton‐coupled‐electron‐transfer reagents.
Petra Vojáčková, Armido Studer
wiley   +2 more sources

Radical Scavenger Properties of Some 1,2-Dithiol Compounds Against Electropolymerization of Aniline

open access: yes, 2010
International audienceThe kinetics of aniline electropolymerization was investigated in acidic H2O/CH3CN solutions and in presence of some 1,2-dithiol compounds.
Darchen, André   +5 more
core   +1 more source

Reaction of Aromatic Amines with Epihalohydrins [PDF]

open access: yes, 1964
Published procedures for the reaction of primary aromatic amines with epihalohydrins to give 1:1 addition compounds are not generally applicable, and we have found that they frequently lead to impure products.
Pennington, F. C., Aniline, Orm
core   +1 more source

Synthesis Of New Asymmetrical Pyromellitdiimides Derived From Pyromellitic Dianhydride

open access: yesIbn Al-Haitham Journal for Pure and Applied Sciences, 2017
This work involves the synthesis and characterization of asymmetrical pyromellitdiimide derivatives [IV]a-f by four sequence steps selective reaction . One mole of pyromellitic dianhydride was reacted with one mole of various primary aromatic amines [
E. T. Ali
doaj  

Palladium Catalyzed Reactions of 2-Nitroaniline with Vinylethers

open access: yesE-Journal of Chemistry, 2007
A new method for the synthesis of hemiaminal ether have been suggested. The reactions of 2-nitro aniline with vinyl ether in the presence of PdCl2(CH3CN)2 produces hemiaminal ether compounds. The resulting products have been identified by spectral data.
Farideh Piri   +2 more
doaj   +1 more source

Sustainable Access to N‐Heterocycles: One‐Pot Cascade Synthesis of Pyrroles From Bio‐Derived Furans

open access: yesAngewandte Chemie, EarlyView.
Highly dispersed platinum (Pt) clusters on Brønsted acid‐rich HY zeolite enable a one‐pot cascade conversion of bio‐derived furans and nitroarenes into pyrroles. Highly dispersed Pt sites ensure selective nitro hydrogenation, while Pt nanoparticles promote undesired over‐hydrogenation.
Haifeng Qi   +5 more
wiley   +2 more sources

Linear competitive inhibition of human tissue kallikrein by 4-aminobenzamidine and benzamidine and linear mixed inhibition by 4-nitroaniline and aniline

open access: yesBrazilian Journal of Medical and Biological Research, 2001
Hydrolysis of D-valyl-L-leucyl-L-arginine p-nitroanilide (7.5-90.0 µM) by human tissue kallikrein (hK1) (4.58-5.27 nM) at pH 9.0 and 37ºC was studied in the absence and in the presence of increasing concentrations of 4-aminobenzamidine (96-576 µM ...
M.O. Sousa   +5 more
doaj   +1 more source

Covalent Organic Framework Colloids With Core‐Shell Donor/Acceptor Architecture and Ultralong‐Lived Charge‐Separated States

open access: yesAngewandte Chemie, EarlyView.
Uniform core‐shell colloidal particles of Covalent Organic Frameworks (COFs) are synthesized by a seeded growth of electron‐acceptor COF shells on electron‐donor COF cores. The resulting p‐n heterojunction enables efficient separation of photogenerated charges, which persist for minutes. These core‐shell COFs show efficient CO2 photoreduction to CO and
Ting Yu   +8 more
wiley   +2 more sources

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