It's a Gas: Bioconjugation With Vapor‐Phase Reagents
Gaseous reagents are an emerging class of bioconjugation reagents that can offer alternative selectivity paradigms for the construction of precise bioconjugates. A variety of both inert and highly reactive gases have recently been developed for bioconjugation use.
Yuxuan Ding, Jun Ohata, Zachary T. Ball
wiley +1 more source
We report an efficient method for late‐stage installation of “clickable” alkyne groups into diverse (hetero)arenes. Using a dual‐ligand palladium catalyst that combines an NASA ligand with an N‐heterocycle, an acrylate unit bearing a terminal alkyne can be introduced via nondirected C─H activation.
Tommaso Braga +2 more
wiley +1 more source
Comprehensive urinary metabolite profiles of workers exposed to aniline, 2,4-dimethylaniline, and 2-methylaniline. [PDF]
Eitaki Y +3 more
europepmc +1 more source
Oxidative degradation of aniline derived compounds over carbon based materials
The objectives of this work were: the preparation of different forms of carbon materials (AC, ACSA, CX, CXSA and GBCM), assessment of their catalytic efficiency in the CWPO of the azo dye Chromotrope 2R. Initially the materials were characterized by several techniques, afterwards adsorption and reaction runs were done and lastly the samples obtained ...
openaire +1 more source
Recent theoretical efforts to elucidate the origin of enantioselectivity in transition metal‐catalyzed propargylic substitution reactions are highlighted in this review. ABSTRACT In recent years, asymmetric catalytic propargylic substitution reactions have undergone remarkable development, enabling the construction of chiral carbon centers adjacent to ...
Ken Sakata, Yoshiaki Nishibayashi
wiley +1 more source
Machine learning-based QSAR modeling assay for the nitrification inhibition of 2,4,5-trichloroaniline-derived eco-friendly Schiff bases. [PDF]
Mondal T +9 more
europepmc +1 more source
Insights into the Photocatalytic Arene Bromination Enabled by Cs2AgBiBr6 Microparticles
A sustainable photocatalytic bromination of electron‐rich arenes is enabled by low‐toxicity Cs2AgBiBr6 double‐perovskite microparticles using HBr as an atom‐economical bromine source. Surface‐derived bromine radicals drive highly selective mono‐bromination under mild conditions.
Daniele Conelli +8 more
wiley +1 more source
Structural properties of hybrid compounds based on aniline derivatives [PDF]
openaire +1 more source
Dihydroquinazolinones by Titanocene‐Catalyzed Reductive Radical Addition to Quinazolinones
Tri‐ and tetracyclic dihydroquinazolinones or quinazolinones by titanocene catalysis: A highly diastereoselective and efficient reductive radical addition to quinazolinones enables an unprecedented entry to pharmaceutically relevant dihydroquinazolinones by avoiding the interception of radical intermediates prior to the slow radical addition.
Thomas Heinrichs +5 more
wiley +1 more source
A Brønsted-based deep eutectic solvent as a green catalyst for the sustainable one-pot synthesis of 1,2,4,5-tetrasubstituted imidazole derivatives: <i>in vitro</i> cytotoxicity and <i>in silico</i> binding studies on HepG2 cells. [PDF]
Ngoc Tran TA +4 more
europepmc +1 more source

