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Manganese‐Based Na‐Rich Materials Boost Anionic Redox in High‐Performance Layered Cathodes for Sodium‐Ion Batteries

Advances in Materials, 2019
To improve the energy and power density of Na‐ion batteries, an increasing number of researchers have focused their attention on activation of the anionic redox process.
Xiaoyu Zhang   +8 more
semanticscholar   +1 more source

The Anion Gap

New England Journal of Medicine, 1977
The anion gap can be readily calculated from routine laboratory data, and although it has its widest application in the diagnosis of various forms of metabolic acidosis,1 , 2 it may sometimes provi...
M S, Oh, H J, Carroll
openaire   +4 more sources

Reduction of a Tetrafluoroterephthalonitrile-β-Cyclodextrin Polymer to Remove Anionic Micropollutants and Perfluorinated Alkyl Substances from Water.

Angewandte Chemie, 2019
Organic micropollutants (MPs) are anthropogenic substances that contaminate water resources at trace concentrations. Many MPs, including per- and polyfluorinated alkyl substances (PFASs), have come under increased scrutiny because of their environmental ...
M. Klemes   +6 more
semanticscholar   +1 more source

Anionic Redox Activity Regulated by Transition Metal in Lithium‐Rich Layered Oxides

Advanced Energy Materials, 2020
The anionic redox activity in lithium‐rich layered oxides has the potential to boost the energy density of lithium‐ion batteries. Although it is widely accepted that the anionic redox activity stems from the orphaned oxygen energy level, its regulation ...
Jun-Hyuk Song   +6 more
semanticscholar   +1 more source

Decoupling the roles of Ni and Co in anionic redox activity of Li-rich NMC cathodes

Nature Materials, 2023
Biao Li   +9 more
semanticscholar   +1 more source

Anionic triazine systems

Dalton Trans., 2004
The synthesis of TAS+ C3N3F4- (1) (TAS+ = (Me2N)3S+) and the reactions of 1 with Me3SiOSiMe3 and Me3SiCF3 to give TAS+ C3N3F2O- (2) and TAS+[(NCF)(NCCF3)(NC(CF3)(2)]- (4) are reported. An isomer of 4, TAS+[(NCCF3)2(NCFCF3)]-, compound 6, was obtained by fluoride ion addition to (CF3CN)3.
Melanie, Kingston   +3 more
openaire   +2 more sources

The Trifluoromethyl Anion

Angewandte Chemie, 2015
AbstractFirst evidence for the existence of free trifluoromethyl anion CF3− has been obtained. The 3D‐caged potassium cation in [K(crypt‐222)]+ is inaccessible to CF3−, thus rendering it uncoordinated (“naked”). Ionic [K(crypt‐222)]+ CF3− has been characterized by single‐crystal X‐ray diffraction, solution NMR spectroscopy, DFT calculations, and ...
Anton, Lishchynskyi   +6 more
openaire   +2 more sources

Understanding the Low-Voltage Hysteresis of Anionic Redox in Na2Mn3O7

Chemistry of Materials, 2019
The large-voltage hysteresis remains one of the biggest barriers to optimizing Li/Na-ion cathodes using lattice anionic redox reaction, despite their very high energy density and relative low cost....
Bohang Song   +18 more
semanticscholar   +1 more source

Precise anionic regulation of NiFe hydroxysulfide assisted by electrochemical reactions for efficient electrocatalysis

, 2020
Highly efficient electrocatalysts with high intrinsic activity for oxygen and sulfur redox reactions are strongly required for sustainable energy systems.
Chang‐Xin Zhao   +6 more
semanticscholar   +1 more source

Anion-π interactions

Chem. Soc. Rev., 2008
This tutorial review provides an overview of the theoretical and experimental investigations that resulted in the recognition of anion-pi interactions, i.e., non-covalent forces between electron deficient aromatic systems and anions. Several pioneering theoretical studies revealed that these interactions are energetically favorable (approximately 20-50
Brandi L, Schottel   +2 more
openaire   +2 more sources

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