Results 11 to 20 of about 51,419 (284)

A route to anionic hydrophilic films of copolymers of l-leucine, l-aspartic acid and l-aspartic acid esters [PDF]

open access: yes, 1975
A series of copolymers of l-leucine and β-benzyl-l-aspartate [Leu/Asp(OBz)] covering the range 30–70 mol % of l-leucine, was synthesized by the N-carboxyanhydride (NCA) method.
Bantjes, A., Feijen, J., Sederel, W.L.
core   +9 more sources

Surface-Initiated Atom Transfer Polymerized Anionic Corona on Gold Nanoparticles for Anti-Cancer Therapy

open access: yesPharmaceutics, 2020
Surface initiated atom transfer radical polymerization (SI-ATRP) documented a simple but efficient technique to grow a dense polymer layer on any surface. Gold nanoparticles (AuNPs) give a broad surface to immobilize sulfhyryl group-containing initiators
Wei Mao   +3 more
doaj   +1 more source

Anionic PPV polymerization from the sulfinyl precursor route: Block copolymer formation from sequential addition of monomers [PDF]

open access: yesPolymer, 2013
The sulfinyl precursor route for the synthesis of poly(p-phenylene vinylene) (PPV) materials via an anionic polymerization procedure employing dedicated initiators is evaluated in depth. Reaction kinetics are investigated to gain more control over the polymerization, since polymerization proceeds to full conversion already on the timescale of mixing of
Cosemans, Inge   +6 more
openaire   +2 more sources

THE INFLUENCE OF SURFACTANT AND PROTECTIVE COLLOID ON POLYVINYL ACETATE EMULSION SYNTHESIZED BY EMULSION POLYMERIZATION TECHNIQUE

open access: yesSpektra: Jurnal Fisika dan Aplikasinya, 2020
A series of experiments have been carried out and reported. This report describes the stages of the polymerization reaction during emulsion Polyvinyl Acetate (PVAc) synthesis.
Adam Jaya   +3 more
doaj   +1 more source

High linoleic waste sunflower oil: A distinctive recycled source of self-healing agent for smart metal coatings

open access: yesHeliyon, 2023
High Linoleic Waste Sunflower Oil (HLWSO) is a new self-healing agent viable to be encapsulated. Meanwhile, the unique mechanism behind the synthesis of microcapsules is deeply illustrated; the emulsification process of HLWSO by anionic surfactant and ...
Z. Baharom   +3 more
doaj   +1 more source

Radical Polymerization of Alkyl 2-Cyanoacrylates

open access: yesMolecules, 2018
Cyanoacrylates (CAs) are well-known fast-setting adhesives, which are sold as liquids in the presence of stabilizers. Rapid anionic polymerization on exposure to surface moisture is responsible for instant adhesion.
Cormac Duffy   +2 more
doaj   +1 more source

Polymerisation via Zwitterionen

open access: yesCHIMIA, 1972
Zwitterions and ylides were for a long time considered to be inadequate to initiate ionic polymerization. Recently however, it has been proved that such reactions are possible.
Hans Zweifel, Theodor Völker
doaj   +1 more source

Self-Assembly of Low-Molecular-Weight Asymmetric Linear Triblock Terpolymers: How Low Can We Go?

open access: yesMolecules, 2020
The synthesis of two (2) novel triblock terpolymers of the ABC type and one (1) of the BAC type, where A, B and C are chemically different segments, such as polystyrene (PS), poly(butadiene) (PB1,4) and poly(dimethylsiloxane) (PDMS), is reported ...
Christina Miskaki   +9 more
doaj   +1 more source

Tuning moduli of hybrid bottlebrush elastomers by molecular architecture

open access: yesMaterials & Design, 2023
Polymeric elastomers made of bottlebrush chains are soft, solvent-free materials with precisely controllable moduli by network topology. However, fabrication methods of bottlebrush networks with precisely programmable topology are lacking.
Vahid Asadi   +3 more
doaj   +1 more source

Chemical analysis and aqueous solution properties of Charged Amphiphilic Block Copolymers PBA-b-PAA synthesized by MADIX [PDF]

open access: yes, 2007
We have linked the structural and dynamic properties in aqueous solution of amphiphilic charged diblock copolymers poly(butyl acrylate)-b-poly(acrylic acid), PBA-b-PAA, synthesized by controlled radical polymerization, with the physico-chemical ...
Berret, J. -F.   +6 more
core   +5 more sources

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