Anionic Polymerization Using Flow Microreactors [PDF]
Molecules, 2019 Flow microreactors are expected to make a revolutionary change in chemical synthesis involving various fields of polymer synthesis. In fact, extensive flow microreactor studies have opened up new possibilities in polymer chemistry including cationic ...
Yusuke Takahashi, Aiichiro Nagaki
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Anionic polymerization of nonaromatic maleimide to achieve full-color nonconventional luminescence [PDF]
Nature Communications, 2022 Nonconventional luminophores without extended π-conjugation is a rising star in the area of luminescent materials but continuously tuning the emission color within a broad visible region via rational molecular design remains challenging.
Xin Ji +6 more
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Anionic polymerization of p-(2,2′-diphenylethyl)styrene and applications to graft copolymers [PDF]
Designed Monomers and Polymers, 2017 Well-controlled anionic polymerization of an initiator-functionalized monomer, p-(2,2′-diphenylethyl)styrene (DPES), was achieved for the first time. The polymerization was performed in a mixed solvent of cyclohexane and tetrahydrofuran (THF) at 40 °C ...
Minglu Huang +4 more
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Synthesis of hypergrafted poly[4-(N,N-diphenylamino)methylstyrene] through tandem anionic-radical polymerization of radical-inimer [PDF]
Designed Monomers and Polymers, 2017 In this paper, we present a tandem anionic-radical approach for synthesizing hypergrafted polymers. We prepared 4-(N,N-diphenylamino)methylstyrene (DPAMS) as a new radical-based inimer.
Minglu Huang +4 more
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Anionic polymerization of vinyl ketones
Die Makromolekulare Chemie, 1963 AbstractStereoregular polymerizations of some vinyl ketones were examined by using several anionic catalysts.Methyl vinyl ketone was found to be polymerized by some catalysts such as calcium zinc tetraethyl and phenylmagnesium bromide (etherate) to give highly crystalline polymers which melt at about 160°C.
Ryota Fujio +2 more
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"Research progress in preparation of thermoplastic elastomers by living controlled polymerization"
Hecheng xiangjiao gongye, 2023 Starting with polymerization methods such as anionic polymerization, cationic polymerization, ring-opening polymerization, and controlled free radical polymerization, the research progress of different types of thermoplastic elastomer synthesis ...
ZHANG hao1, ZHANG Hua-qiang2, LIU Ruo-fan1, ZHAO Zhi-chao2, JIN Yu-shun1, LI Fu-chong2, WU Yi-bo1
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Utilization of steric hindrance of alkyl lithium-based initiator to synthesize high 1,4 unit-containing hydroxyl- terminated polybutadiene [PDF]
Royal Society Open Science, 2018 A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized.
Xin Min, Xiaodong Fan, Jie Liu
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Progress in dilithium initiators for anionic polymerization
Hecheng xiangjiao gongye, 2023 "The different types, synthesis methods and characteristics of dihalogenated alkanes, naphthalenes, diolefins and their oligomers, as well as other new types of dilithium initiators for anionic polymerization were summarized with 34 references. "
JING Meng-na1,2, DONG Jing2, ZHANG Ding-jun1
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Preparation of Acrylamide-based Anionic Polyelectrolytes for Soil Establishment [PDF]
علوم و تکنولوژی پلیمر, 2012 Synthetic water soluble acrylamide-based polymers have wide range of ap-plications in the feld of soil establishment and non-desertifcation.
Ahmad Rabiee +2 more
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A route to anionic hydrophilic films of copolymers of l-leucine, l-aspartic acid and l-aspartic acid esters [PDF]
, 1975 A series of copolymers of l-leucine and β-benzyl-l-aspartate [Leu/Asp(OBz)] covering the range 30–70 mol % of l-leucine, was synthesized by the N-carboxyanhydride (NCA) method.
Bantjes, A., Feijen, J., Sederel, W.L.
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