Results 101 to 110 of about 24,607 (305)

Simultaneous Polymerization by Cationic and Anionic Catalysts [PDF]

open access: yes, 1969
In our previous paper simultaneous cationic and anionic polymerizations have been reported to proceed in the case of the graft copolymerization of β-propiolactone with Nvinyl carbazole onto the trunk polymers containing -SO₃ Na or -COOH groups.
SHIOTA, Tetsuya   +2 more
core  

Ultrafast phosphazene-promoted controlled anionic polymerization of styrenic monomers

open access: yes, 2019
The anionic polymerization of styrenic monomers with phosphazene bases as promoters, utilizing “seeding” technique in a nonpolar solvent and at room temperature was studied.
Bilalis, Panagiotis   +5 more
core   +1 more source

Electrode and Microstructure Dependence of Oxygen Diffusion in Ferroelectric Hafnium Zirconium Oxide Thin Films

open access: yesAdvanced Functional Materials, EarlyView.
Significant nanoscale oxygen diffusion coefficient variations are measured in ferroelectric hafnium zirconium oxide films with grain boundaries and electrode interfaces exhibiting values 104 times larger than the grain cores. Overall coefficients are 10X larger for films prepared with metal nitride electrodes compared to refractory metals. New insights
Liron Shvilberg   +6 more
wiley   +1 more source

Moving Beyond Oligoethers: Polar Side‐Chain Engineering for Aqueous Mixed Ionic–Electronic Conductors

open access: yesAdvanced Functional Materials, EarlyView.
We investigate how side‐chain chemistry and hydrogen bonding affect electrochemical doping in poly(propylenedioxythiophene) polymers. Replacing oligoether side chains with hydroxyl or carboxylic acid groups nearly triples electrochemical conductivity.
Joshua M. Rinehart   +5 more
wiley   +1 more source

GPC Observations of Branching Effects in Anionic Polymerization of Methyl Methacrylate: A Preliminary Study

open access: yes, 2010
[[abstract]]The anionic polymerization of methyl methacrylate was performed ill tetrahydrofuran (THF) at -78 degrees C, using sec-butyllithium/1,1-diphenylethylene (DPE) as the initiation system.
Tsai, Y (Tsai, Yuhsin); Wu, JH (Wu, Jyh-Horng); Tsai, FJ (Tsai, Fuu-Jen)
core  

Anionic polymerization of Z,Z-2,4hexadienedinitrile

open access: yes, 1982
Z,Z-2,4-Hexadienedinitrile, synthesized by the oxidative cleavage of o-phenylenediamine, was found to undergo anionic polymerization with n-BuLi in DMF at room temperature or below.
Kalyanam, N.   +2 more
core   +1 more source

Dual‐Function Interface Engineering for δ‐Phase‐Free Crystallization Toward Efficient and Stable FAPbI3 Perovskite Solar Cells

open access: yesAdvanced Functional Materials, EarlyView.
This work presents a dual‐function interface engineering strategy using PEACl to suppress the formation of the non‐perovskite δ‐FAPbI3 phase at the critical SnO2 buried interface. This approach enables the direct crystallization of the photoactive α‐phase, yielding highly efficient and stable rigid (25.6%) and flexible perovskite solar cells with ...
Xiao Wu   +7 more
wiley   +1 more source

Novel Poly(ethylene oxide) Grafted Polycarbazole Conjugated Freestanding Network Films via Anionic and Electrochemical Polymerization

open access: yesInternational Journal of Electrochemical Science, 2013
Novel electroactive conjugated network of poly(ethylene oxide) grafted polycarbazole freestanding film poly[poly(N-epoxypropyl carbazole)] (PPEPC) was successfully achieved via anionic ring-open polymerization of N-epoxypropyl carbazole (EPC) and ...
Leiqiang Qin   +6 more
doaj   +1 more source

New perspectives in living/controlled anionic polymerization

open access: yes, 2005
Control of the reactivity and selectivity of active species remains a major challenge in the course of living/controlled polymerizations of vinyl and heterocyclic monomers.
DESBOIS, Philippe   +2 more
core  

Exciton Binding Energy of Phosphorescent Emitter Molecules in Organic Light‐Emitting Diodes

open access: yesAdvanced Functional Materials, EarlyView.
Energy level alignment is key to efficient OLED design, yet determining LUMO energies remains challenging. A methodology based on field‐induced dissociation and kinetic Monte Carlo simulations is presented to extract LUMO energies of iridium‐based phosphorescent emitters from their exciton binding energy.
Hiroki Tomita   +6 more
wiley   +1 more source

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