Results 121 to 130 of about 24,607 (305)

Backbone‐Controlled Ion‐Side Chain Accessibility in Conjugated Polymers for Organic Electrochemical Synaptic Transistors

open access: yesAdvanced Functional Materials, EarlyView.
Backbone modulation in glycolated conjugated polymers governs ion accessibility to side chains, strengthes anion adsorption, and suppresses back‐diffusion. As the number of thiophene units increases, structural reorganization, retention, and synaptic plasticity are enhanced, leading to improved neuromorphic performance in electrolyte‐gated organic ...
Junho Sung   +10 more
wiley   +1 more source

Methacrylic stereoblock copolymers via the combination of catalytic chain transfer and anionic polymerization

open access: yes, 2011
A novel synthetic pathway toward stereoblock copolymers by combining catalytic chain transfer polymerization with anionic polymerization is described. Catalytic chain transfer polymerization (CCTP) has been used to synthesize vinyl-terminated polymers ...
Sciarone, T.J.J.   +10 more
core   +1 more source

Spectroscopic Investigation of Polysulfide Redox Evolution in Catholyte Solutions for Potassium–Sulfur Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Potassium–sulfur batteries are investigated using UV–vis spectroscopy to track the evolution of potassium polysulfide species at elevated temperature. The study reveals sulfur radical anions as key intermediates and shows how solvent composition and cell design influence polysulfide stability, redox behavior, and cycling performance, providing insights
Chiara Morini   +7 more
wiley   +1 more source

Temperature-modulated separation of vascular cells using thermoresponsive-anionic block copolymer-modified glass

open access: yesRegenerative Therapy
Introduction: Vascular tissue engineering is a key technology in the field of regenerative medicine. In tissue engineering, the separation of vascular cells without cell modification is required, as cell modifications affect the intrinsic properties of ...
Tadashi Hirotani, Kenichi Nagase
doaj   +1 more source

Effects of enchained ester groups on the living carbocationic polymerization of vinyl ethers

open access: yes
A series of chloro - substituted 4-(ethenyloxy)butyl benzoate and acetate monomers were polymerized in toluene at -20 and 4o C using an HCl etherate / ethylaluminum dichloride (EtAlCl2) initiator system in the presence and absence of an externally added ...
Shepherd, Walter
core  

Anionic polymerization of styrene in ionic liquids

open access: yes, 2008
Anionic polymerization of styrene in ionic ...
R Vijayaraghavan (13406664)   +2 more
core  

Methacrylic Stereoblock Copolymers via the Combination of Catalytic Chain Transfer and Anionic Polymerization

open access: yes, 2016
A novel synthetic pathway toward stereoblock copolymers by combining catalytic chain transfer polymerization with anionic polymerization is described. Catalytic chain transfer polymerization (CCTP) has been used to synthesize vinyl-terminated polymers ...
Johan P. A. Heuts (2055190)   +4 more
core   +1 more source

Engineering Pendant Group Chemistry to Control Hydrophilicity and Oxidative Degradation of Thioketal‐Based Biomaterials

open access: yesAdvanced Functional Materials, EarlyView.
Thioketal (TK) polymers are promising biomaterials due to their selective biodegradation by reactive oxygen species (ROS), but they respond slowly to physiologic doses of ROS. Here, the TK bond's pendant groups are modified to enhance the degradation of TK‐based implants both in vitro and in vivo.
Karina A. Bruce   +6 more
wiley   +1 more source

Understanding the Morphologies and Polymerization Mechanism of Homopolymer and Block Copolymer Brushes by Living Anionic Surface Initiated Polymerization

open access: yes, 2002
Homopolymer and block copolymer brushes grafted from Au and Si (SiOx) surfaces via living anionic surface initiated polymerization (LASIP) has been reported. 1,1-diphenylethylene (DPE) derivative, an initiator for anionic polymerization, was grafted onto
George Sakellariou   +5 more
core   +1 more source

Nanoengineered Binetworks in Multifunctional Anionic Block Polymer Mesoblends for Improved Mechanical Properties

open access: yesAdvanced Functional Materials, EarlyView.
Mesoblends consist of a nanostructured polymer into which a second polymer is imbibed with a selective solvent. In this work, a solvent‐templatable pentablock terpolymer possessing a sulfonated midblock is modified with a hydrophilic polymer that is photocrosslinked in situ, yielding a hierarchical binetwork.
Kacie M. Wells   +3 more
wiley   +1 more source

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