Structural and Thermodynamic Understandings in Mn‐Based Sodium Layered Oxides during Anionic Redox [PDF]
Advanced Science, 2020 A breakthrough utilizing an anionic redox reaction (O2−/On−) for charge compensation has led to the development of high‐energy cathode materials in sodium‐ion batteries.
Seok Mun Kang +11 more
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Boosting reversible anionic redox reaction with Li/Cu dual honeycomb centers
EScience, 2023 The anionic redox reaction (ARR) is a promising charge contributor to improve the reversible capacity of layered-oxide cathodes for Na-ion batteries; however, some practical bottlenecks still need to be eliminated, including a low capacity retention ...
Feixiang Ding
exaly +3 more sources
Configuration‐dependent anionic redox in cathode materials
Battery Energy, 2022 The utilization of anionic redox is one of the most prospective strategies to obtain high specific capacities in addition to the transition metal redox.
Lu Yang, Rusong Chen, Zepeng Liu
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Activation of anionic redox in d0 transition metal chalcogenides by anion doping [PDF]
Nature Communications, 2021 Activation of anionic redox in battery materials promises great benefits for battery materials, but remains an elusive phenomenon. Here, the authors present anion-doping as a novel strategy to unlock electrochemical activity in the cobalt/nickel free ...
Bernhard T. Leube +11 more
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Transition Metal Slab Gliding: One Key Process for Activating Anionic Redox Reaction in P2‐Type Transition Metal Oxide Cathodes [PDF]
Advanced ScienceAnionic redox chemistry is crucial for determining the capacity and stability of layered oxide cathodes for Na‐ion batteries. However, the driving forces of anionic redox remain elusive.
Dongxiao Wang +12 more
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Transition metal vacancy and position engineering enables reversible anionic redox reaction for sodium storage [PDF]
Nature CommunicationsTriggering the anionic redox reaction is an effective approach to boost the capacity of layered transition metal (TM) oxides. However, the irreversible oxygen release and structural deterioration at high voltage remain conundrums.
Congcong Cai +13 more
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Metastability and Reversibility of Anionic Redox-Based Cathode for High-Energy Rechargeable Batteries [PDF]
Cell Reports Physical Science, 2020 Summary: Great focus has recently been placed on anionic redox, to which high capacities of Li-rich layered oxides are attributed. With almost doubled capacity compared with state-of-the-art cathode materials, Li-rich layered oxides still fall short in ...
Bao Qiu +11 more
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Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide [PDF]
Nature Communications, 2017 The rational design of intercalation electrodes is largely confined to the optimization of redox chemistry of transition metals and oxygen. Here, the authors report the single anionic redox process in NaCrS2 where it is sulfur rather than chromium that ...
Zulipiya Shadike +10 more
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Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S [PDF]
Nature Communications, 2019 Anionic redox reactions are gaining interest as a means to optimize capacities of alkaline ion batteries. Here, the authors investigate various charge compensation mechanisms and report S–S dimerization and the formation of electron holes on sulfur in a ...
Tian Wang +12 more
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Anionic Redox Topochemistry for Materials Design: Chalcogenides and Beyond [PDF]
ACS Organic & Inorganic Au, 2023 Shunsuke Sasaki +3 more
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