Anion–anion and anion–neutral triel bonds
Physical Chemistry Chemical Physics, 2021 TrCl4−(Tr = Al, Ga, In, Tl) anion is able to engage in complexes with two Lewis bases: neutral NH3or the CN−anion through a triel bond. Complexation leads to two types of geometries: axial and equatorial.
Rafał Wysokiński +3 more
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Anion⋅⋅⋅Anion Interactions Involving σ‐Holes of Perrhenate, Pertechnetate and Permanganate Anions [PDF]
ChemPhysChem, 2021 AbstractIn this communication experimental and theoretical results are reported affording strong evidence that interactions between electron rich atoms and the metal of tetroxide anions of group 7 elements are a new case of attractive and σ‐hole interactions.
Andrea Daolio +4 more
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Design and Investigation of Superatoms for Redox Applications: First-Principles Studies
Micromachines, 2023 A superatom is a cluster of atoms that acts like a single atom. Two main groups of superatoms are superalkalis and superhalogens, which mimic the chemistry of alkali and halogen atoms, respectively.
Celina Sikorska
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Anion⋅⋅⋅Anion Coinage Bonds: The Case of Tetrachloridoaurate [PDF]
Angewandte Chemie, 2021 AbstractInteractions in crystalline tetrachloridoaurates of acetylcholine and dimethylpropiothetine are characterized by Au⋅⋅⋅Cl and Au⋅⋅⋅O short contacts. The former interactions assemble the AuCl4− units into supramolecular anionic polymers, while the latter interactions append the acetylcholine and propiothetine units to the polymer.
Andrea Daolio +5 more
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Molecules, 2022 To be detectable in space via radio astronomy, molecules should have a permanent dipole moment. This is the plausible reason why HCnH chains are underproportionally represented in the interstellar medium in comparison with the isoelectronically ...
Ioan Bâldea
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Dynamics of the Chemical Composition of Precipitation and Input of Elements in an Agricultural Area in Southern Bulgaria [PDF]
Bulgarian Journal of Soil Science, 2023 The study of the chemical composition of precipitation is an important factor in determining the input of elements and the total anthropogenic load in agroecosystems.
Tsetska Simeonova, Lyuba Nenova
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Anion Colorimetric Chemosensor Based on a Benzimidazole-Functionalized BODIPY Derivative
Chemistry Proceedings, 2022 A BODIPY derivative bearing a benzimidazole unit at position 2 and an electron donor group (anthracene) at the meso position was synthetized and characterized by the usual spectroscopic techniques.
Raquel C. R. Gonçalves +3 more
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Anions coordinating anions: analysis of the interaction between anionic Keplerate nanocapsules and their anionic ligands [PDF]
Physical Chemistry Chemical Physics, 2017 The interaction strength between Keplerates and anionic ligands depends on their pKa and solvation/desolvation effects.
Dolores Melgar +3 more
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Frontiers in Chemistry, 2022 Using DFT/(B3LYP/wB97XD/B2PLYPD) and OVGF electronic structure methods with flexible atomic orbital basis sets, we examined the series of polynuclear superhalogen anions matching the (BF3(BN)nF4n+1)– formula (for n = 1-10,13,18-20) containing alternately
Adrianna Cyraniak +4 more
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Development of ion chromatography methods for the determination of trace anions in ultra pure water from power plants [PDF]
Journal of the Serbian Chemical Society, 2005 A suppressed ion chromatography (IC) technique, using a carbonate/hydrogen carbonate or a hydroxide eluent, has been evaluated as a monitoring tool for the detection of major anions (F-, Cl-, NO3-, PO43- and SO42-) in ultra pure water and condensed steam
Čičkarić Dragana Z. +3 more
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