Results 91 to 100 of about 9,739 (288)

Synthesis of Highly Fluorinated 2,2′-Biphenols and 2,2′-Bisanisoles

open access: yes, 2016
Multiply fluorine-substituted iodo anisoles are efficiently coupled in an Ullmann-type reaction to provide the corresponding bisanisoles. The coupling is selective and even tolerates bromo moieties.
Siegfried R. Waldvogel (1434088)   +2 more
core   +1 more source

Controlled Formation and Unusual Reactivity of Cyanohexatriyne (HC7N), a Synthetically Challenging Interstellar Cyanopolyyne

open access: yesChemistry – A European Journal, Volume 32, Issue 38, 13 October 2026.
First controlled formation of cyanohexatriyne (HC7N) is achieved using a cobalt–alkyne masking strategy that overcomes the intrinsic instability of nitrile‐substituted polyynes. The approach enables spectroscopic validation of HC7N and reveals its pronounced electrophilicity through a selective conjugate addition with diethylamine.
Léa Lefrançois   +4 more
wiley   +1 more source

Fate of pentachlorophenol-14C in rice plants under controlled conditions.

open access: yes, 1982
Pentachlorophenol-14C was applied to soil (23 kg/ha), and rice plants were grown over two vegetation periods under flooded conditions. The uptake of radioactivity by plants was 12.9% in the first and 2.5% in the second year.
Korte, F.   +4 more
core   +1 more source

Synthesis of S‐Arylthioxanthonium Trifluoromethanesulfonates From Thioxanthones and Diaryliodonium Salts by Copper(II) Catalysis and Application to Aryl–Heteroaryl Bond Formation by Direct LED Irradiation

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 38, 13 October 2026.
A straightforward Cu(II)‐catalyzed synthesis of S‐arylthioxanthonium trifluoromethanesulfonates from readily available thioxanthones and diaryliodonium salts is described. A broad range of salts is obtained in moderate to good yields. It is further demonstrated that S‐arylthioxanthonium trifluoromethanesulfonates act as aryl radical precursors under ...
Pierre Boulay   +2 more
wiley   +1 more source

Conversion of Alcohols to Alkyl Chlorides Using the Bichloride Ionic Liquid [NEt3Me][Cl(HCl)n]

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 38, 13 October 2026.
The ionic liquid [NEt3Me][Cl(HCl)1.61] is presented as a controllable source of HCl for the effective transformation of a broad range of alcohols into alkyl chlorides. The process eliminates the need for continuous handling of HCl gas and enables a recyclable IL‐based catalyst system. The solvent‐free chlorination of alcohols using the bichloride‐based
Justus H. Peter   +8 more
wiley   +1 more source

Benchmark thermodynamic properties of methylanisoles: Experimental and theoretical study

open access: yes, 2020
© 2015 Elsevier Ltd. All rights reserved. Accurate standard molar enthalpy of formation values in the liquid phase can be obtained by combining high-level quantum chemistry values of gas-phase enthalpies of formation with experimentally determined ...
Zaitseva K.   +4 more
core  

On the Structure of Gaseous Anisole. [PDF]

open access: yesActa Chemica Scandinavica, 1973
H. M. Seip   +4 more
openaire   +1 more source

Efficient Dibromination of Aromatics with Fe(NO3)3·9H2O/FeBr3

open access: yesSynOpen
Wenfei Yang   +9 more
doaj   +1 more source

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