Flavin Catalysts in Organic Synthesis
Flavins and their congeners are potent catalysts for organic synthesis inspired by enzymatic transformations. In addition to catalysis in the flavin ground state via covalent intermediates, the excited singlet and triplet states unlock applications including photooxidation, photoreduction, and energy transfer via sensitization.
Jan Freudenberg, Golo Storch
wiley +2 more sources
A library of 25 novel estrogen analogues were prepared in five to eight steps from mostly commercially available substituted anisoles via bromination, formylation, Corey-Fuchs reaction, elimination, and Sonogashira ...
Krimmelbein, Ilga Kristine +7 more
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Establishing de novo microbial biosynthesis of anisole [PDF]
Lyon Bruinsma +5 more
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Hydrogenolysis of Aromatic Oxygenates Over Pt/WO3–ZrO2 in a Water/Decane Biphasic System
Combining a water‐tolerant Pt/WO3–ZrO2 catalyst with a water/decane biphasic system enables efficient hydrogenolysis of lignin‐derived aromatic oxygenates under mild conditions. Spatial separation of the catalyst and arene products suppresses over‐hydrogenation, providing high aromatic selectivity at only 90 °C and 0.1 atm H2.
Akito Ai +6 more
wiley +1 more source
A one‐shot Pd(II)‐catalyzed C─H activation strategy enables the rapid conversion of simple linear propiolamides into structurally diverse mono‐, di‐, and tri‐olefin‐bridged MPAEs. This cascade process orchestrates up to six sequential C–H activations in a single operation, providing streamlined access to highly conjugated architectures.
Haiyu Wang +4 more
wiley +1 more source
Evaluating the host potential of 9,9’-bifluorenyl-9,9’-diol for anisole and the three methylanisole isomers, and its behaviour in mixed guest solutions [PDF]
Benita Barton +2 more
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Benchmark thermodynamic properties of methylanisoles: Experimental and theoretical study [PDF]
© 2015 Elsevier Ltd. All rights reserved. Accurate standard molar enthalpy of formation values in the liquid phase can be obtained by combining high-level quantum chemistry values of gas-phase enthalpies of formation with experimentally determined ...
Zaitseva K. +4 more
core
Ortho- and Para-Selective Ruthenium-Catalyzed C(sp )-H Oxygenations of Phenol Derivatives
Versatile ruthenium catalysts allowed for efficient direct oxygenations of aryl carbamates under remarkably mild reaction conditions. In addition to chelation-assisted C-H activation, the optimized ruthenium catalyst proved amenable to para-selective ...
Liu, Weiping, Ackermann, Lutz
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Starting from carboxylic acids and Selectfluor‐derivatives, functionalized diazabicyclooctanes can be obtained via a novel Polonovski‐type rearrangement proceeding under mild reaction conditions. Besides their use in organic synthesis the unique structure and reactivity of the rearrangement products enables applications in medicinal chemistry ...
Jakob Kuhn +5 more
wiley +1 more source
Substituent-driven electronic structure, nonlinear optical response, and tubulin binding of anisole- and spiro-isatin-functionalized benzo[4,5-e]pyran derivatives: An integrated experimental and computational investigation [PDF]
Paul Daniel Jebaraj +6 more
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