Results 61 to 70 of about 9,739 (288)
A 3-step asymmetric approach toward the optically active chiral cyclohex-2-enones from anisoles has been developed. The crucial asymmetric induction step is an unprecedented catalytic enantioselective isomerization of β,γ-unsaturated cyclohex-3-en-1-ones
Jung Hwa Lee (196293), Li Deng (442821)
core +1 more source
A molecular design strategy combines lignin‐derived aromatic units, sugar‐derived furan groups, and flexible glycol segments to create wet‐spinnable polyurethanes. Thermally reversible Diels–Alder crosslinking chemistry enables formation of crosslinked thermosetting fibers, repeated de‐crosslinking/re‐crosslinking cycles, and tunable fiber properties ...
Rafael N. L. Menezes +7 more
wiley +1 more source
NMR-spectroscopic study of conjugation effects. 8.13C NMR spectra of p-substituted anisoles, thioanisoles, and selenoanisoles [PDF]
1. According to the data from13C NMR spectra, the effective conformation of anisoles, thioanisoles, and selenoanisoles is determined both by "methyl-ring" spatial interactions as well as by p, π conjugation of the O, S, and Se with the aromatic fragment ...
Lipovich T. +6 more
core
One-Step Preparation of Some 3-Substituted Anisoles
A one-step preparation of 3-bromoanisole, 3-chloroanisole, and 3-trifluoromethylanisole from the corresponding 3-substituted nitrobenzenes is carried out by nucleophilic aromatic substitution of the nitro group with sodium or potassium methoxide ...
Joseph Zilberman (2529262)
core +1 more source
1,2‐Bis(boronate) Arenes by Borylation Directed Borylation
Boron electrophiles derived from tetrabromo‐pyrazaboles and AlCl3 affect the regioselective vicinal double C–H borylation of a range of arenes and polycyclic aromatic hydrocarbons (PAHs). A subsequent pinacol installation step then affords the vicinal bis‐boronate ester‐substituted arene/PAH.
Anna V. Schellbach +4 more
wiley +2 more sources
Cl NQR Studies in 2,4,6-, 2,3,6-, and 2,3,4-Trichloro Anisoles
The chlorine-35 NQR frequencies and their temperature variation in 2,4,6-, 2,3,6- and 2,3,4-trichloro anisoles have been studied and compared with the corresponding chlorophenols with a view to studying the effect of hydrogen bonding.
Rukmani, K, Ramakrishna, J
core
Some spectroscopic, kinetic and equilibria studies of Cyano- and nitro- substituted anisoles and phenols and their reactions with nucleophiles [PDF]
The reactions of ring-activated alkyl aryl ethers with nucleophiles have been examined. The main pathways involve attack by the nucleophiles at the alkyl carbon to give substituted phenoxide ions, or at ring carbon atoms to give σ-adducts.
Castilho, Paula C.M.F.
core
Efficient persistent deep‐red emission is achieved in purely organic systems at elevated donor concentrations via triplet–singlet Förster‐resonance energy transfer. A high phosphorescence quantum yield of 53.6% is obtained at 10 wt% donor loading, and remains as high as 37.2% even at 30 wt%.
Rongjuan Huang +2 more
wiley +1 more source
Anisoles 4 react with AlCl3 and PCl3 to yield the new fused bicyclic system derivatives 5 and 6 as major products in a one-pot procedure. An alternative multi-step synthesis of this system is also reported in which bis(o-methoxyaryl)phosphane oxides 11 ...
Bazzocchi M., Boga C., Baccolini G.
core +1 more source
A transpiration‐inspired Janus nanofiber membrane creates a persistent dry‐wet interface that couples localized solar heating with hydration‐induced ion regulation. The asymmetric architecture sustains directional water and ion transport, suppresses salt accumulation, and enables simultaneous seawater evaporation and stable electricity generation ...
Qin Su +10 more
wiley +1 more source

