S,O-Ligand Promoted meta-C−H Arylation of Anisole Derivatives via Palladium/Norbornene Catalysis [PDF]
Angew Chem Int Ed Engl, 2022 Reversing the conventional site-selectivity of C−H activation processes provides new retrosynthetic disconnections to otherwise unreactive bonds. Here, we report a new catalytic system based on palladium/norbornene and an S,O-ligand for the meta-C−H ...
Fernández-Ibáñez, M.Á. +3 more
core +2 more sources
Conversion of Alcohols into Amides Using Alumina-Methanesulfonic Acid (AMA) in Nitrile Solvents [PDF]
Iranian Journal of Chemistry & Chemical Engineering, 1999 The reaction of tertiary, secondary and benzylic alcohols with different nitriles in the presence of alumina-methanesulfonic acid (AMA) as a new reagent affords the corresponding amides in good yields (Table 1, 2).
Hashem Sharghi, Khodabakhsh Niknam
doaj
Group additive modeling of substituent effects in monocyclic aromatic hydrocarbon radicals [PDF]
, 2017 The thermodynamic properties of the unsubstituted and substituted phenyl, phenoxy, anisyl, benzoyl, styryl and benzyl radicals with six substituents (hydroxy, methoxy, formyl, vinyl, methyl, and ethyl) are calculated with the bond additivity corrected ...
Benson SW. +5 more
core +3 more sources
Microextraction and gas chromatography/mass spectrometry for improved analysis of geosmin and other fungal "off" volatiles in grape juice [PDF]
, 2010 Geosmin is a volatile fungal metabolite with an earthy aroma produced in grape products from rotten grapes. The accumulation of geosmin in grapes is caused by the interaction of Botrytis cinerea and Penicillium expansum.
Lima, Nelson +5 more
core +1 more source
Experimental and kinetic modeling study of pyrolysis and combustion of anisole [PDF]
, 2018 open7siFast biomass pyrolysis is an effective process with high yields of bio-oil, and is a promising technology to partially replace non-renewable fossil fuels.
Faravelli, Tiziano +6 more
core +2 more sources
Ynones in dearomative spirocyclisation processes; a review
Tetrahedron ChemThis review concentrates on our research into the discovery of novel ynone-based dearomative spirocyclisation processes, whilst placing the new chemistry into the context of existing knowledge.
Richard J.K. Taylor, William P. Unsworth
doaj +1 more source
Prevention and control of contaminants of industrial processes and pesticides in the poultry production chain [PDF]
, 2002 The reduction in levels of organochlorine pesticide residues in food of animal origin in the past 30 years has been achieved especially by controlling entrance via the feed chain.
Kan, C.A.
core +4 more sources
The furan microsolvation blind challenge for quantum chemical methods: First steps [PDF]
, 2018 © 2018 Author(s). Herein we present the results of a blind challenge to quantum chemical methods in the calculation of dimerization preferences in the low temperature gas phase.
Al-Mogren, Muneerah M. +27 more
core +4 more sources
Advanced Functional Materials, EarlyView.AgCrP2S6 reveals a momentum‐indirect band edge (≈1.35 eV) and chain‐locked linear dichroism: the first direct transitions emerge at 1.6–1.8 eV for E||a. Resonant Raman and photoemission corroborate this assignment. In ACPS/graphene heterostructures, photocurrent turns on above ≈1.5 eV and follows the same polarization selection rules (anisotropy ≈0.53),
Oleksandr Volochanskyi +9 more
wiley +1 more source
Alkoxysulfonium Salts Unlock Access to New Aryl Sulfonium Salts for Cross‐Coupling
Angewandte Chemie, EarlyView.Hard‐to‐access (hetero)aryl sulfonium salts are prepared using stable methoxysulfonium salts in combination with the magnesiation of (hetero)aryl bromides. The approach allows access to aryl sulfonium salts bearing electron‐deficient (hetero)aryl rings, or electron‐rich aryl motifs in which the sulfonium motif resides at an alternative position on the ...
Rachel E. Brown +4 more
wiley +2 more sources