Chemical Syntheses of 3′ and 5′ Phosphorylated Oligonucleotides: An Overview
This review provides an overview of the various chemical methods employed in the synthesis of oligonucleotides bearing a phosphate group at their 3′ or 5′ end. Notably, it presents modified phosphoramidites and supports developed for this purpose. Oligonucleotides (ON) with a phosphate monoester group at their 3′ or 5′ end have applications in many ...
Rémy Lartia
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Room-temperature structure determination of vacuum-sensitive organic compounds by formvar encapsulation and serial electron diffraction. [PDF]
Pulleri Vadhyar S +4 more
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Lighting the Path to Cyclic Phosphonamides via Halogen‐Bond Electron Donor–Acceptor Activation
Cyclic phosphinamides are valuable scaffolds for optoelectronic applications, yet remain difficult to access with existing methods. Here, we highlight a mild and straightforward visible light‐driven strategy that enables the formation of cyclic phosphinamides and thiophosphinamides.
Clara Faure +8 more
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Cavity Constriction and Chiralization of Polyaromatic Subnanotubes via Post-assembly Ligand/Metal Modification. [PDF]
Yamato S +5 more
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Molecular crystals must withstand both isotropic and anisotropic stress to function in flexible optoelectronics and high‐pressure devices. In situ high‐pressure single‐crystal X‐ray diffraction coupled with DFT‐D computations reveal how an emissive molecular crystal with interdigitated packing bends elastically at ambient‐pressure and remains ...
Arif H. Dar +10 more
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MXene@Cu-BTC/PPy Carbon with MWCNTs@MoS<sub>2</sub> Hierarchical Composite for Electrochemical Detection of Anthracene and Phenanthrene in Licorice. [PDF]
Li Y +6 more
europepmc +1 more source
Machine learning and free energy clustering reveal PAH protein binding linked to AD risk. [PDF]
Chen C +5 more
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Cellular Effects and Regulated Protein Expression of MCF-7 Breast Cancer Cells Following Exposure to PAH Derivative 3-Hydroxybenz[a]anthracene. [PDF]
Kang X, Song W, Li X, Yang Y, Wu X.
europepmc +1 more source
Ion‐Pairing and Counterion Effects in Contemporary Photochemistry
Ion‐pairing and counterion effects have emerged as fundamental yet underexplored determinants of photochemical behavior. Far from inert, counterions, and Coulombic interactions modulate excited‐state dynamics, quenching efficiencies, emission, and catalytic pathways.
Matthias Schmitz, Christoph Kerzig
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Synthon Substitution via C-I···π and C-I···N Halogen Bonds in Cocrystals of Anthracene-Based Organic Semiconductor Isosteres. [PDF]
Bondarenko I +3 more
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